X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold

Xiangqun Zeng; Shiva Prasad; Stanley Bruckenstein

doi:10.1021/la971067b

X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold

Xiangqun Zeng
, Shiva Prasad
, Stanley Bruckenstein

Chemistry

SUNY Buffalo
Universidade Federal da Paraíba

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy successfully clarified the processes occurring on gold electrode surface that accompany coulostatic underpotential deposition (UPD) of mercury. They showed that a sulfur-containing species was adsorbed. It corresponded to the adsorption of 28% Hg(I) bisulfate on the gold during the UPD process. This work confirmed Shay and Bruckenstein's deductions, based on electrochemical quartz crystal microbalance studies, that 34% Hg(I) bisulfate was adsorbed.

Original language	English
Pages (from-to)	2535-2540
Number of pages	6
Journal	Langmuir
Volume	14
Issue number	9
DOIs	https://doi.org/10.1021/la971067b
State	Published - Apr 28 1998

Access to Document

10.1021/la971067b

Fingerprint

Dive into the research topics of 'X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold'. Together they form a unique fingerprint.

Cite this

@article{051c3a2b4f574a5c9dbff87fbf4e219e,

title = "X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold",

abstract = "Time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy successfully clarified the processes occurring on gold electrode surface that accompany coulostatic underpotential deposition (UPD) of mercury. They showed that a sulfur-containing species was adsorbed. It corresponded to the adsorption of 28\% Hg(I) bisulfate on the gold during the UPD process. This work confirmed Shay and Bruckenstein's deductions, based on electrochemical quartz crystal microbalance studies, that 34\% Hg(I) bisulfate was adsorbed.",

author = "Xiangqun Zeng and Shiva Prasad and Stanley Bruckenstein",

year = "1998",

month = apr,

day = "28",

doi = "10.1021/la971067b",

language = "English",

volume = "14",

pages = "2535--2540",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "9",

}

X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold. / Zeng, Xiangqun; Prasad, Shiva; Bruckenstein, Stanley.
In: Langmuir, Vol. 14, No. 9, 28.04.1998, p. 2535-2540.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold

AU - Zeng, Xiangqun

AU - Prasad, Shiva

AU - Bruckenstein, Stanley

PY - 1998/4/28

Y1 - 1998/4/28

N2 - Time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy successfully clarified the processes occurring on gold electrode surface that accompany coulostatic underpotential deposition (UPD) of mercury. They showed that a sulfur-containing species was adsorbed. It corresponded to the adsorption of 28% Hg(I) bisulfate on the gold during the UPD process. This work confirmed Shay and Bruckenstein's deductions, based on electrochemical quartz crystal microbalance studies, that 34% Hg(I) bisulfate was adsorbed.

AB - Time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy successfully clarified the processes occurring on gold electrode surface that accompany coulostatic underpotential deposition (UPD) of mercury. They showed that a sulfur-containing species was adsorbed. It corresponded to the adsorption of 28% Hg(I) bisulfate on the gold during the UPD process. This work confirmed Shay and Bruckenstein's deductions, based on electrochemical quartz crystal microbalance studies, that 34% Hg(I) bisulfate was adsorbed.

UR - https://www.scopus.com/pages/publications/0032051014

U2 - 10.1021/la971067b

DO - 10.1021/la971067b

M3 - Article

AN - SCOPUS:0032051014

SN - 0743-7463

VL - 14

SP - 2535

EP - 2540

JO - Langmuir

JF - Langmuir

IS - 9

ER -

X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry study of Hg(I) and sulfate adsorption processes accompanying the coulostatic underpotential deposition of mercury on gold

Abstract

Access to Document

Other files and links

Fingerprint

Cite this