Vibrational predissociation in the hydrogen fluoride dimer

Robert L. DeLeon; J. S. Muenter

doi:10.1063/1.446708

Vibrational predissociation in the hydrogen fluoride dimer

Robert L. DeLeon
, J. S. Muenter

Center for Computational Research

University of Rochester

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

A color center IR laser was used to excite the proton-accepting monomer of a HF dimer in a molecular beam. The maximum excess linewidth arising from vibrational predissociation was 10 MHz, indicating a vibrational predissociation lifetime of ≥30 ns. The maximum lifetime was estimated to be 300 ns from intensity considerations.

Original language	English
Pages (from-to)	6092-6094
Number of pages	3
Journal	Journal of Chemical Physics
Volume	80
Issue number	12
DOIs	https://doi.org/10.1063/1.446708
State	Published - 1983

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title = "Vibrational predissociation in the hydrogen fluoride dimer",

abstract = "A color center IR laser was used to excite the proton-accepting monomer of a HF dimer in a molecular beam. The maximum excess linewidth arising from vibrational predissociation was 10 MHz, indicating a vibrational predissociation lifetime of ≥30 ns. The maximum lifetime was estimated to be 300 ns from intensity considerations.",

author = "DeLeon, \{Robert L.\} and Muenter, \{J. S.\}",

year = "1983",

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journal = "Journal of Chemical Physics",

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AU - DeLeon, Robert L.

AU - Muenter, J. S.

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AB - A color center IR laser was used to excite the proton-accepting monomer of a HF dimer in a molecular beam. The maximum excess linewidth arising from vibrational predissociation was 10 MHz, indicating a vibrational predissociation lifetime of ≥30 ns. The maximum lifetime was estimated to be 300 ns from intensity considerations.

UR - https://www.scopus.com/pages/publications/36549096412

U2 - 10.1063/1.446708

DO - 10.1063/1.446708

M3 - Article

AN - SCOPUS:36549096412

SN - 0021-9606

VL - 80

SP - 6092

EP - 6094

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

Vibrational predissociation in the hydrogen fluoride dimer

Abstract

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