Ultralarge and thermally stable electro-optic activities from supramolecular self-assembled molecular glasses

Tae Dong Kim; Jae Wook Kang; Jingdong Luo; Sei Hum Jang; Jae Won Ka; Neil Tucker; Jason B. Benedict; Larry R. Dalton; Tomoko Gray; René M. Overney; Dong Hun Park; Warren N. Herman; Alex K.Y. Jen

doi:10.1021/ja067970s

Ultralarge and thermally stable electro-optic activities from supramolecular self-assembled molecular glasses

Tae Dong Kim
, Jae Wook Kang
, Jingdong Luo
, Sei Hum Jang
, Jae Won Ka
, Neil Tucker
, Jason B. Benedict
, Larry R. Dalton
, Tomoko Gray
, René M. Overney
, Dong Hun Park
, Warren N. Herman
, Alex K.Y. Jen

Chemistry

University of Washington
University of Maryland, College Park

Research output: Contribution to journal › Article › peer-review

334 Scopus citations

Abstract

A series of molecular engineered organic glasses have been prepared to exploit the use of complementary Ar-Ar^F interactions to improve poling efficiency. These self-organized molecular glasses have also been used as host in the binary chromophore system to further improve the number density of chromophores and r₃₃ values. Ultrahigh r₃₃ values (up to 327 pm/V at the wavelength of 1310 nm) and good temporal stability could be achieved in these materials.

Original language	English
Pages (from-to)	488-489
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	3
DOIs	https://doi.org/10.1021/ja067970s
State	Published - Jan 24 2007

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Kim, T. D., Kang, J. W., Luo, J., Jang, S. H., Ka, J. W., Tucker, N., Benedict, J. B., Dalton, L. R., Gray, T., Overney, R. M., Park, D. H., Herman, W. N., & Jen, A. K. Y. (2007). Ultralarge and thermally stable electro-optic activities from supramolecular self-assembled molecular glasses. Journal of the American Chemical Society, 129(3), 488-489. https://doi.org/10.1021/ja067970s

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title = "Ultralarge and thermally stable electro-optic activities from supramolecular self-assembled molecular glasses",

abstract = "A series of molecular engineered organic glasses have been prepared to exploit the use of complementary Ar-ArF interactions to improve poling efficiency. These self-organized molecular glasses have also been used as host in the binary chromophore system to further improve the number density of chromophores and r33 values. Ultrahigh r33 values (up to 327 pm/V at the wavelength of 1310 nm) and good temporal stability could be achieved in these materials.",

author = "Kim, \{Tae Dong\} and Kang, \{Jae Wook\} and Jingdong Luo and Jang, \{Sei Hum\} and Ka, \{Jae Won\} and Neil Tucker and Benedict, \{Jason B.\} and Dalton, \{Larry R.\} and Tomoko Gray and Overney, \{Ren{\'e} M.\} and Park, \{Dong Hun\} and Herman, \{Warren N.\} and Jen, \{Alex K.Y.\}",

year = "2007",

month = jan,

day = "24",

doi = "10.1021/ja067970s",

language = "English",

volume = "129",

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AU - Kim, Tae Dong

AU - Kang, Jae Wook

AU - Luo, Jingdong

AU - Jang, Sei Hum

AU - Ka, Jae Won

AU - Tucker, Neil

AU - Benedict, Jason B.

AU - Dalton, Larry R.

AU - Gray, Tomoko

AU - Overney, René M.

AU - Park, Dong Hun

AU - Herman, Warren N.

AU - Jen, Alex K.Y.

PY - 2007/1/24

Y1 - 2007/1/24

N2 - A series of molecular engineered organic glasses have been prepared to exploit the use of complementary Ar-ArF interactions to improve poling efficiency. These self-organized molecular glasses have also been used as host in the binary chromophore system to further improve the number density of chromophores and r33 values. Ultrahigh r33 values (up to 327 pm/V at the wavelength of 1310 nm) and good temporal stability could be achieved in these materials.

AB - A series of molecular engineered organic glasses have been prepared to exploit the use of complementary Ar-ArF interactions to improve poling efficiency. These self-organized molecular glasses have also been used as host in the binary chromophore system to further improve the number density of chromophores and r33 values. Ultrahigh r33 values (up to 327 pm/V at the wavelength of 1310 nm) and good temporal stability could be achieved in these materials.

UR - https://www.scopus.com/pages/publications/33846419517

U2 - 10.1021/ja067970s

DO - 10.1021/ja067970s

M3 - Article

AN - SCOPUS:33846419517

SN - 0002-7863

VL - 129

SP - 488

EP - 489

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 3

ER -

Ultralarge and thermally stable electro-optic activities from supramolecular self-assembled molecular glasses

Abstract

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