Time-resolved mono-anion, di-anion, and solvent transfers into a poly(vinylferrocene)-modified electrode

Stanley Bruckenstein; Alexander T. Fensore; A. Robert Hillman

doi:10.1149/1.1838269

Time-resolved mono-anion, di-anion, and solvent transfers into a poly(vinylferrocene)-modified electrode

Stanley Bruckenstein
, Alexander T. Fensore
, A. Robert Hillman

Chemistry

SUNY Buffalo
University of Leicester
The Electrochemical Society

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

We describe dynamic dual quartz crystal microbalance measurements of redox driven ion and solvent transfers between poly(vinylferrocene) films and aqueous disodium naphthalene-1,5-disulfonate solutions. The relative transport rates are dianion > monoanion > solvent; salt does not participate. Solvent expulsion is faster than solvent entry. On short time scales during oxidation only dianion motion responds to electron transfer.

Original language	English
Pages (from-to)	L24-L26
Journal	Journal of the Electrochemical Society
Volume	145
Issue number	2
DOIs	https://doi.org/10.1149/1.1838269
State	Published - Feb 1998

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10.1149/1.1838269

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title = "Time-resolved mono-anion, di-anion, and solvent transfers into a poly(vinylferrocene)-modified electrode",

abstract = "We describe dynamic dual quartz crystal microbalance measurements of redox driven ion and solvent transfers between poly(vinylferrocene) films and aqueous disodium naphthalene-1,5-disulfonate solutions. The relative transport rates are dianion > monoanion > solvent; salt does not participate. Solvent expulsion is faster than solvent entry. On short time scales during oxidation only dianion motion responds to electron transfer.",

author = "Stanley Bruckenstein and Fensore, \{Alexander T.\} and Hillman, \{A. Robert\}",

year = "1998",

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doi = "10.1149/1.1838269",

language = "English",

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T1 - Time-resolved mono-anion, di-anion, and solvent transfers into a poly(vinylferrocene)-modified electrode

AU - Bruckenstein, Stanley

AU - Fensore, Alexander T.

AU - Hillman, A. Robert

PY - 1998/2

Y1 - 1998/2

N2 - We describe dynamic dual quartz crystal microbalance measurements of redox driven ion and solvent transfers between poly(vinylferrocene) films and aqueous disodium naphthalene-1,5-disulfonate solutions. The relative transport rates are dianion > monoanion > solvent; salt does not participate. Solvent expulsion is faster than solvent entry. On short time scales during oxidation only dianion motion responds to electron transfer.

AB - We describe dynamic dual quartz crystal microbalance measurements of redox driven ion and solvent transfers between poly(vinylferrocene) films and aqueous disodium naphthalene-1,5-disulfonate solutions. The relative transport rates are dianion > monoanion > solvent; salt does not participate. Solvent expulsion is faster than solvent entry. On short time scales during oxidation only dianion motion responds to electron transfer.

UR - https://www.scopus.com/pages/publications/0032002557

U2 - 10.1149/1.1838269

DO - 10.1149/1.1838269

M3 - Article

AN - SCOPUS:0032002557

SN - 0013-4651

VL - 145

SP - L24-L26

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

IS - 2

ER -

Time-resolved mono-anion, di-anion, and solvent transfers into a poly(vinylferrocene)-modified electrode

Abstract

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