Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4

Jason B. Benedict; Anna Makal; Jesse D. Sokolow; Elzbieta Trzop; Stephan Scheins; Robert Henning; Timothy Graber; Philip Coppens

doi:10.1039/c0cc04997b

Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh₂(μ-PNP)₂(PNP)₂·BPh₄

Jason B. Benedict
, Anna Makal
, Jesse D. Sokolow
, Elzbieta Trzop
, Stephan Scheins
, Robert Henning
, Timothy Graber
, Philip Coppens

Chemistry

SUNY Buffalo
Aarhus University
The University of Chicago

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) Å is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.

Original language	English
Pages (from-to)	1704-1706
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	6
DOIs	https://doi.org/10.1039/c0cc04997b
State	Published - Jan 27 2011

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Benedict, J. B., Makal, A., Sokolow, J. D., Trzop, E., Scheins, S., Henning, R., Graber, T., & Coppens, P. (2011). Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh₂(μ-PNP)₂(PNP)₂·BPh₄. Chemical Communications, 47(6), 1704-1706. https://doi.org/10.1039/c0cc04997b

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title = "Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4",

abstract = "The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) {\AA} is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.",

author = "Benedict, \{Jason B.\} and Anna Makal and Sokolow, \{Jesse D.\} and Elzbieta Trzop and Stephan Scheins and Robert Henning and Timothy Graber and Philip Coppens",

year = "2011",

month = jan,

day = "27",

doi = "10.1039/c0cc04997b",

language = "English",

volume = "47",

pages = "1704--1706",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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}

Benedict, JB, Makal, A, Sokolow, JD, Trzop, E, Scheins, S, Henning, R, Graber, T & Coppens, P 2011, 'Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh₂(μ-PNP)₂(PNP)₂·BPh₄', Chemical Communications, vol. 47, no. 6, pp. 1704-1706. https://doi.org/10.1039/c0cc04997b

Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh₂(μ-PNP)₂(PNP)₂·BPh₄. / Benedict, Jason B.; Makal, Anna; Sokolow, Jesse D. et al.
In: Chemical Communications, Vol. 47, No. 6, 27.01.2011, p. 1704-1706.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Time-resolved Laue diffraction of excited species at atomic resolution

T2 - 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4

AU - Benedict, Jason B.

AU - Makal, Anna

AU - Sokolow, Jesse D.

AU - Trzop, Elzbieta

AU - Scheins, Stephan

AU - Henning, Robert

AU - Graber, Timothy

AU - Coppens, Philip

PY - 2011/1/27

Y1 - 2011/1/27

N2 - The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) Å is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.

AB - The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) Å is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.

UR - https://www.scopus.com/pages/publications/79251476880

U2 - 10.1039/c0cc04997b

DO - 10.1039/c0cc04997b

M3 - Article

C2 - 21210070

AN - SCOPUS:79251476880

SN - 1359-7345

VL - 47

SP - 1704

EP - 1706

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh₂(μ-PNP)₂(PNP)₂·BPh₄

Abstract

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