THERMAL ANALYSIS OF GRAPHITE INTERCALATED WITH BROMINE.

D. D.L. Chung

THERMAL ANALYSIS OF GRAPHITE INTERCALATED WITH BROMINE.

D. D.L. Chung

Department of Mechanical and Aerospace Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

A review is presented of thermoanalytical work on graphite intercalated with bromine. By thermal electron diffraction, thermal x-ray diffraction and differential scanning calorimetry, the melting transformation was observed reversibly at 374 K and was found to be a continuous transition. By thermogravimetric analysis, intercalate desorption was found to behave as the outdiffusion of the intercalate, with an activation energy of 17 kcal/mol below the melting temperature and 4 kcal/mol above the melting temperature. The rate of desorption was enhanced by melting.

Original language	English
Title of host publication	Unknown Host Publication Title
Editors	Bernard Miller
Publisher	John Wiley & Sons
Pages	418-428
Number of pages	11
ISBN (Print)	0471262447
State	Published - 1982

Cite this

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title = "THERMAL ANALYSIS OF GRAPHITE INTERCALATED WITH BROMINE.",

abstract = "A review is presented of thermoanalytical work on graphite intercalated with bromine. By thermal electron diffraction, thermal x-ray diffraction and differential scanning calorimetry, the melting transformation was observed reversibly at 374 K and was found to be a continuous transition. By thermogravimetric analysis, intercalate desorption was found to behave as the outdiffusion of the intercalate, with an activation energy of 17 kcal/mol below the melting temperature and 4 kcal/mol above the melting temperature. The rate of desorption was enhanced by melting.",

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year = "1982",

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AU - Chung, D. D.L.

PY - 1982

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N2 - A review is presented of thermoanalytical work on graphite intercalated with bromine. By thermal electron diffraction, thermal x-ray diffraction and differential scanning calorimetry, the melting transformation was observed reversibly at 374 K and was found to be a continuous transition. By thermogravimetric analysis, intercalate desorption was found to behave as the outdiffusion of the intercalate, with an activation energy of 17 kcal/mol below the melting temperature and 4 kcal/mol above the melting temperature. The rate of desorption was enhanced by melting.

AB - A review is presented of thermoanalytical work on graphite intercalated with bromine. By thermal electron diffraction, thermal x-ray diffraction and differential scanning calorimetry, the melting transformation was observed reversibly at 374 K and was found to be a continuous transition. By thermogravimetric analysis, intercalate desorption was found to behave as the outdiffusion of the intercalate, with an activation energy of 17 kcal/mol below the melting temperature and 4 kcal/mol above the melting temperature. The rate of desorption was enhanced by melting.

UR - https://www.scopus.com/pages/publications/0020217597

M3 - Conference contribution

AN - SCOPUS:0020217597

SN - 0471262447

SP - 418

EP - 428

BT - Unknown Host Publication Title

A2 - Miller, Bernard

PB - John Wiley & Sons

ER -

THERMAL ANALYSIS OF GRAPHITE INTERCALATED WITH BROMINE.

Abstract

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