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Theoretical and experimental studies of photorefractivity in novel polymeric composites

  • Bogdan Swedek
  • , Paras N. Prasad
  • , Yiping Cui
  • , Ning Cheng
  • , Jaroslaw W. Zieba
  • , Jeffrey Winiarz
  • , Kie Soo Kim
  • SUNY Buffalo

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

4 Scopus citations

Abstract

We present results of temperature dependence studies of photorefractive effect in a polymeric composite PVK:TCP:C 60:DEANST. At elevated temperature, decreased rigidity of the host matrix leading to increased orientational mobility of the second-order nonlinear chromophores results in enhanced photorefractive performance. Diffraction efficiency approaching 100% and enhanced two-beam coupling gain coefficients are reported. The influence of temperature on the speed of photorefractive response is measured and discussed. We also report on a novel photorefractive polymeric composite. A new chromophore, 4-[N-(2- hydroxyethyl)-N-(methyl)amino phenyl]-4'-(6-hydroxyhexyl sulfonyl)stilbene, abbreviated as APSS, possessing high transparency over a broad wavelength, is used together with a PVK:TCP:C 60 matrix. This composite shows high photorefractive figures of merit at 488, 514.5 and 632.8 nm. Diffraction efficiencies up to 40%, as well as net two-beam coupling gains of 60 cm -1 have been achieved at these wavelengths.

Original languageEnglish
Title of host publicationProceedings of SPIE - The International Society for Optical Engineering
EditorsStephen Ducharme, James W. Stasiak
Pages89-99
Number of pages11
StatePublished - 1996
EventOrganic Photorefractive Materials and Xerographic Photoreceptors - Denver, CO, USA
Duration: Aug 7 1996Aug 8 1996

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume2850
ISSN (Print)0277-786X

Conference

ConferenceOrganic Photorefractive Materials and Xerographic Photoreceptors
CityDenver, CO, USA
Period08/7/9608/8/96

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