The temperature dependent luminescent decay kinetics of an emissive copper complex in the single crystalline phase using time-gated luminescence microscopy

Crysania M. Linderman; Jarrett A. Coppin; Corey O'Brien; Jordan M. Cox; Dinesh G. Patel; Jason B. Benedict

doi:10.1016/j.jlumin.2015.12.027

The temperature dependent luminescent decay kinetics of an emissive copper complex in the single crystalline phase using time-gated luminescence microscopy

Crysania M. Linderman
, Jarrett A. Coppin
, Corey O'Brien
, Jordan M. Cox
, Dinesh G. Patel
, Jason B. Benedict

Chemistry

SUNY Buffalo
Pennsylvania State University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu(dmp)(PPh₃)₂]BF₄ (dmp=2,9-dimethyl-1,10-phenanthroline and PPh₃=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition.

Original language	English
Pages (from-to)	30-33
Number of pages	4
Journal	Journal of Luminescence
Volume	173
DOIs	https://doi.org/10.1016/j.jlumin.2015.12.027
State	Published - May 2016

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10.1016/j.jlumin.2015.12.027

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title = "The temperature dependent luminescent decay kinetics of an emissive copper complex in the single crystalline phase using time-gated luminescence microscopy",

abstract = "The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu(dmp)(PPh3)2]BF4 (dmp=2,9-dimethyl-1,10-phenanthroline and PPh3=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition.",

author = "Linderman, \{Crysania M.\} and Coppin, \{Jarrett A.\} and Corey O'Brien and Cox, \{Jordan M.\} and Patel, \{Dinesh G.\} and Benedict, \{Jason B.\}",

year = "2016",

month = may,

doi = "10.1016/j.jlumin.2015.12.027",

language = "English",

volume = "173",

pages = "30--33",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

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T1 - The temperature dependent luminescent decay kinetics of an emissive copper complex in the single crystalline phase using time-gated luminescence microscopy

AU - Linderman, Crysania M.

AU - Coppin, Jarrett A.

AU - O'Brien, Corey

AU - Cox, Jordan M.

AU - Patel, Dinesh G.

AU - Benedict, Jason B.

PY - 2016/5

Y1 - 2016/5

N2 - The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu(dmp)(PPh3)2]BF4 (dmp=2,9-dimethyl-1,10-phenanthroline and PPh3=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition.

AB - The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu(dmp)(PPh3)2]BF4 (dmp=2,9-dimethyl-1,10-phenanthroline and PPh3=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition.

UR - https://www.scopus.com/pages/publications/84954443466

U2 - 10.1016/j.jlumin.2015.12.027

DO - 10.1016/j.jlumin.2015.12.027

M3 - Article

AN - SCOPUS:84954443466

SN - 0022-2313

VL - 173

SP - 30

EP - 33

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

The temperature dependent luminescent decay kinetics of an emissive copper complex in the single crystalline phase using time-gated luminescence microscopy

Abstract

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