The photophysics of 6-(1-pyrenyl)hexyl-11(1-pyrenyl)undecanoate dissolved in organic liquids and supercritical carbon dioxide: Impact on olefin metathesis

Siddharth Pandey; Maureen A. Kane; Gary A. Baker; Frank V. Bright; Alois Fürstner; Günter Seidel; Walter Leitner

doi:10.1021/jp011497h

The photophysics of 6-(1-pyrenyl)hexyl-11(1-pyrenyl)undecanoate dissolved in organic liquids and supercritical carbon dioxide: Impact on olefin metathesis

Siddharth Pandey
, Maureen A. Kane
, Gary A. Baker
, Frank V. Bright
, Alois Fürstner
, Günter Seidel
, Walter Leitner

Chemistry

New Mexico Institute of Mining and Technology
SUNY Buffalo
Max Planck Institute for Coal Research

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The photophysics of 6-(1-pyrenyl) hexyl-11(1-pyrenyl) undecanoate dissolved in organic liquids and supercritical carbon dioxide was discussed. The cyclic product was formed in excellent yeild when the CO₂ density was high. Oligomers were formed by an acyclic diene metathesis (ADMET) pathway at lower CO₂ densities. The results suggest that changes in the CO₂ density lead to change in the intra- vs intermolecular interactions between the 16-membered diene dissolved in supercritical carbon dioxide.

Original language	English
Pages (from-to)	1820-1832
Number of pages	13
Journal	Journal of Physical Chemistry B
Volume	106
Issue number	7
DOIs	https://doi.org/10.1021/jp011497h
State	Published - Feb 21 2002

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title = "The photophysics of 6-(1-pyrenyl)hexyl-11(1-pyrenyl)undecanoate dissolved in organic liquids and supercritical carbon dioxide: Impact on olefin metathesis",

abstract = "The photophysics of 6-(1-pyrenyl) hexyl-11(1-pyrenyl) undecanoate dissolved in organic liquids and supercritical carbon dioxide was discussed. The cyclic product was formed in excellent yeild when the CO2 density was high. Oligomers were formed by an acyclic diene metathesis (ADMET) pathway at lower CO2 densities. The results suggest that changes in the CO2 density lead to change in the intra- vs intermolecular interactions between the 16-membered diene dissolved in supercritical carbon dioxide.",

author = "Siddharth Pandey and Kane, \{Maureen A.\} and Baker, \{Gary A.\} and Bright, \{Frank V.\} and Alois F{\"u}rstner and G{\"u}nter Seidel and Walter Leitner",

year = "2002",

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doi = "10.1021/jp011497h",

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T1 - The photophysics of 6-(1-pyrenyl)hexyl-11(1-pyrenyl)undecanoate dissolved in organic liquids and supercritical carbon dioxide

T2 - Impact on olefin metathesis

AU - Pandey, Siddharth

AU - Kane, Maureen A.

AU - Baker, Gary A.

AU - Bright, Frank V.

AU - Fürstner, Alois

AU - Seidel, Günter

AU - Leitner, Walter

PY - 2002/2/21

Y1 - 2002/2/21

N2 - The photophysics of 6-(1-pyrenyl) hexyl-11(1-pyrenyl) undecanoate dissolved in organic liquids and supercritical carbon dioxide was discussed. The cyclic product was formed in excellent yeild when the CO2 density was high. Oligomers were formed by an acyclic diene metathesis (ADMET) pathway at lower CO2 densities. The results suggest that changes in the CO2 density lead to change in the intra- vs intermolecular interactions between the 16-membered diene dissolved in supercritical carbon dioxide.

AB - The photophysics of 6-(1-pyrenyl) hexyl-11(1-pyrenyl) undecanoate dissolved in organic liquids and supercritical carbon dioxide was discussed. The cyclic product was formed in excellent yeild when the CO2 density was high. Oligomers were formed by an acyclic diene metathesis (ADMET) pathway at lower CO2 densities. The results suggest that changes in the CO2 density lead to change in the intra- vs intermolecular interactions between the 16-membered diene dissolved in supercritical carbon dioxide.

UR - https://www.scopus.com/pages/publications/0037149156

U2 - 10.1021/jp011497h

DO - 10.1021/jp011497h

M3 - Article

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SN - 1520-6106

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SP - 1820

EP - 1832

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 7

ER -

The photophysics of 6-(1-pyrenyl)hexyl-11(1-pyrenyl)undecanoate dissolved in organic liquids and supercritical carbon dioxide: Impact on olefin metathesis

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