The electroduction of nitrite in 0.1 M HClO4 at platinum

R. Rao Gadde; Stanley Bruckenstein

doi:10.1016/S0022-0728(74)80148-8

The electroduction of nitrite in 0.1 M HClO₄ at platinum

R. Rao Gadde
, Stanley Bruckenstein

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

The reduction of nitrite at platinum electrode in 0.1 M HClO₄ leads to a number of products. At 0.5 V, detectable amounts of NO are found. In the potential range 0.4 to 0.3 V, N₂O is produced at a high current efficiency. At -0.22 V, nitrite is reduced in net 4 electron convective-diffusion limited process. The products of this reduction are about 60.7% NH₂OH, 18.8% N₂O and 21.6% NH₃.

Original language	English
Pages (from-to)	163-174
Number of pages	12
Journal	Journal of Electroanalytical Chemistry
Volume	50
Issue number	2
DOIs	https://doi.org/10.1016/S0022-0728(74)80148-8
State	Published - Feb 25 1974

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title = "The electroduction of nitrite in 0.1 M HClO4 at platinum",

abstract = "The reduction of nitrite at platinum electrode in 0.1 M HClO4 leads to a number of products. At 0.5 V, detectable amounts of NO are found. In the potential range 0.4 to 0.3 V, N2O is produced at a high current efficiency. At -0.22 V, nitrite is reduced in net 4 electron convective-diffusion limited process. The products of this reduction are about 60.7\% NH2OH, 18.8\% N2O and 21.6\% NH3.",

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N2 - The reduction of nitrite at platinum electrode in 0.1 M HClO4 leads to a number of products. At 0.5 V, detectable amounts of NO are found. In the potential range 0.4 to 0.3 V, N2O is produced at a high current efficiency. At -0.22 V, nitrite is reduced in net 4 electron convective-diffusion limited process. The products of this reduction are about 60.7% NH2OH, 18.8% N2O and 21.6% NH3.

AB - The reduction of nitrite at platinum electrode in 0.1 M HClO4 leads to a number of products. At 0.5 V, detectable amounts of NO are found. In the potential range 0.4 to 0.3 V, N2O is produced at a high current efficiency. At -0.22 V, nitrite is reduced in net 4 electron convective-diffusion limited process. The products of this reduction are about 60.7% NH2OH, 18.8% N2O and 21.6% NH3.

UR - https://www.scopus.com/pages/publications/0542389193

U2 - 10.1016/S0022-0728(74)80148-8

DO - 10.1016/S0022-0728(74)80148-8

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AN - SCOPUS:0542389193

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JO - Journal of Electroanalytical Chemistry

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ER -

The electroduction of nitrite in 0.1 M HClO₄ at platinum

Abstract

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