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Template-assisted cross olefin metathesis

  • SUNY Buffalo

Research output: Contribution to journalArticlepeer-review

57 Scopus citations

Abstract

Making ends meet: Alkene units tethered to two complementary oligoamide strands, which pair sequence-specifically into hydrogen-bonded duplexes, undergo intermolecular cross-metathesis when the two alkene moieties are in close proximity upon heating in the presence of Grubbs' catalyst (see graphic).

Original languageEnglish
Pages (from-to)1352-1356
Number of pages5
JournalAngewandte Chemie - International Edition
Volume44
Issue number9
DOIs
StatePublished - Feb 18 2005

Keywords

  • Alkenes
  • C-C coupling
  • Hydrogen bonds
  • Noncovalent interactions
  • Template synthesis

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