Tandem dienyne cross-metathesis/ring-closing metathesis

Jason A. Smulik; Steven T. Diver

doi:10.1016/S0040-4039(00)01922-5

Tandem dienyne cross-metathesis/ring-closing metathesis

Jason A. Smulik
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Tandem enyne cross-metathesis/ring-closing metathesis between terminal alkynes and 1,5-hexadiene has been demonstrated using the 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium benzylidene complex. Synthesis of 2-substituted 1,3-cyclohexadienes using this one step tandem reaction is reported. In addition, metathesis products were subjected to [4+2] cycloaddition with N-methylmaleimide yielding the corresponding cycloadducts in one synthetic step.

Original language	English
Pages (from-to)	171-174
Number of pages	4
Journal	Tetrahedron Letters
Volume	42
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(00)01922-5
State	Published - Jan 8 2001

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abstract = "Tandem enyne cross-metathesis/ring-closing metathesis between terminal alkynes and 1,5-hexadiene has been demonstrated using the 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium benzylidene complex. Synthesis of 2-substituted 1,3-cyclohexadienes using this one step tandem reaction is reported. In addition, metathesis products were subjected to [4+2] cycloaddition with N-methylmaleimide yielding the corresponding cycloadducts in one synthetic step.",

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AU - Diver, Steven T.

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N2 - Tandem enyne cross-metathesis/ring-closing metathesis between terminal alkynes and 1,5-hexadiene has been demonstrated using the 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium benzylidene complex. Synthesis of 2-substituted 1,3-cyclohexadienes using this one step tandem reaction is reported. In addition, metathesis products were subjected to [4+2] cycloaddition with N-methylmaleimide yielding the corresponding cycloadducts in one synthetic step.

AB - Tandem enyne cross-metathesis/ring-closing metathesis between terminal alkynes and 1,5-hexadiene has been demonstrated using the 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium benzylidene complex. Synthesis of 2-substituted 1,3-cyclohexadienes using this one step tandem reaction is reported. In addition, metathesis products were subjected to [4+2] cycloaddition with N-methylmaleimide yielding the corresponding cycloadducts in one synthetic step.

UR - https://www.scopus.com/pages/publications/0035825031

U2 - 10.1016/S0040-4039(00)01922-5

DO - 10.1016/S0040-4039(00)01922-5

M3 - Article

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VL - 42

SP - 171

EP - 174

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 2

ER -

Tandem dienyne cross-metathesis/ring-closing metathesis

Abstract

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