Synthesis, Structure, and 199Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (MesDPM) Complexes

Lukas Erlemeier; Phoebe R. Hertler; Guang Wu; Xiulan Xie; Jochen Autschbach; Leonardo A. Schenberg; Lucas C. Ducati; Trevor W. Hayton; Carsten von Hänisch

doi:10.1002/chem.202501460

Synthesis, Structure, and ¹⁹⁹Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (^MesDPM) Complexes

Lukas Erlemeier
, Phoebe R. Hertler
, Guang Wu
, Xiulan Xie
, Jochen Autschbach
, Leonardo A. Schenberg
, Lucas C. Ducati
, Trevor W. Hayton
, Carsten von Hänisch

Chemistry

University of Marburg
University of California at Santa Barbara
Universidade de São Paulo

Research output: Contribution to journal › Article › peer-review

Abstract

In this work, we describe the easy synthesis of mercury complexes with the 1,5,9-trimesityldipyrromethene (^MesDPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single-crystal X-ray diffraction analysis (SC-XRD) experiments. In addition, the ¹⁹⁹Hg NMR chemical shifts were determined by measurements and quantum chemical calculations.

Original language	English
Article number	e202501460
Journal	Chemistry - A European Journal
Volume	31
Issue number	40
DOIs	https://doi.org/10.1002/chem.202501460
State	Published - Jul 17 2025

Keywords

Hg NMR
coordination
dipyrrin
dipyrromethene
mercury
transition metal

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10.1002/chem.202501460

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title = "Synthesis, Structure, and 199Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (MesDPM) Complexes",

abstract = "In this work, we describe the easy synthesis of mercury complexes with the 1,5,9-trimesityldipyrromethene (MesDPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single-crystal X-ray diffraction analysis (SC-XRD) experiments. In addition, the 199Hg NMR chemical shifts were determined by measurements and quantum chemical calculations.",

keywords = "Hg NMR, coordination, dipyrrin, dipyrromethene, mercury, transition metal",

author = "Lukas Erlemeier and Hertler, \{Phoebe R.\} and Guang Wu and Xiulan Xie and Jochen Autschbach and Schenberg, \{Leonardo A.\} and Ducati, \{Lucas C.\} and Hayton, \{Trevor W.\} and \{von H{\"a}nisch\}, Carsten",

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month = jul,

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doi = "10.1002/chem.202501460",

language = "English",

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T1 - Synthesis, Structure, and 199Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (MesDPM) Complexes

AU - Erlemeier, Lukas

AU - Hertler, Phoebe R.

AU - Wu, Guang

AU - Xie, Xiulan

AU - Autschbach, Jochen

AU - Schenberg, Leonardo A.

AU - Ducati, Lucas C.

AU - Hayton, Trevor W.

AU - von Hänisch, Carsten

PY - 2025/7/17

Y1 - 2025/7/17

N2 - In this work, we describe the easy synthesis of mercury complexes with the 1,5,9-trimesityldipyrromethene (MesDPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single-crystal X-ray diffraction analysis (SC-XRD) experiments. In addition, the 199Hg NMR chemical shifts were determined by measurements and quantum chemical calculations.

AB - In this work, we describe the easy synthesis of mercury complexes with the 1,5,9-trimesityldipyrromethene (MesDPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single-crystal X-ray diffraction analysis (SC-XRD) experiments. In addition, the 199Hg NMR chemical shifts were determined by measurements and quantum chemical calculations.

KW - Hg NMR

KW - coordination

KW - dipyrrin

KW - dipyrromethene

KW - mercury

KW - transition metal

UR - https://www.scopus.com/pages/publications/105009525290

U2 - 10.1002/chem.202501460

DO - 10.1002/chem.202501460

M3 - Article

C2 - 40522901

AN - SCOPUS:105009525290

SN - 0947-6539

VL - 31

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 40

M1 - e202501460

ER -

Synthesis, Structure, and ¹⁹⁹Hg Chemical Shifts of Mercury 1,5,9-trimesityldipyrromethene (^MesDPM) Complexes

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