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Synthesis, spectral data, and crystal structure of two novel substitution patterns in dithiaporphyrins

  • Youngjae You
  • , Thalia S. Daniels
  • , Paulina M. Dominiak
  • , Michael R. Detty
  • SUNY Buffalo

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The syntheses, characterizations and crystal structures of 5-(4-tert-butylphenyl)-15,20-diphenyl-10-(4-methoxy)phenyl-21, 23-dithiaporphyrin (1b) and 2,3-dimethoxy-10,15-diphenyl-21,23-dithiaporphyrin (2) are described. The cyclization of 2-[1-(4-methoxyphenyl)-1-pyrrolomethyl]-5- (1-phenyl-1-pyrrolomethyl)thiophene and 2-[1-(4-t-butylphenyl)-1-hydroxymethyl]- 5-(1-phenyl-1-hydroxymethyl)thiophene gave predominantly the cis-regioisomer, which was characterized by X-ray crystallography.

Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalJournal of Porphyrins and Phthalocyanines
Volume11
Issue number1
DOIs
StatePublished - 2007

Keywords

  • Core-modified porphyrin
  • Spectral data
  • Synthesis
  • X-ray crystal structure

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