Synthesis of tri(m-sulfonatedphenyl)phosphine (TPPTS): The importance of pH in the work-up

Sven Hida; Paul J. Roman; Allen A. Bowden; Jim D. Atwood

doi:10.1080/00958979808230447

Synthesis of tri(m-sulfonatedphenyl)phosphine (TPPTS): The importance of pH in the work-up

Sven Hida
, Paul J. Roman
, Allen A. Bowden
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Controlling the pH during workup allows synthesis of TPPTS, P(m-C₆H₄SO₃Na)₃, without interference from the oxide. The recrystallized yield is 70% based on P(m-C₆H₄SO₃Na)₃·3H ₂O from PPh₃.

Original language	English
Pages (from-to)	345-348
Number of pages	4
Journal	Journal of Coordination Chemistry
Volume	43
Issue number	4
DOIs	https://doi.org/10.1080/00958979808230447
State	Published - 1998

Keywords

Sulfonated ligands
TPPTS
Water soluble

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10.1080/00958979808230447

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title = "Synthesis of tri(m-sulfonatedphenyl)phosphine (TPPTS): The importance of pH in the work-up",

abstract = "Controlling the pH during workup allows synthesis of TPPTS, P(m-C6H4SO3Na)3, without interference from the oxide. The recrystallized yield is 70\% based on P(m-C6H4SO3Na)3·3H 2O from PPh3.",

keywords = "Sulfonated ligands, TPPTS, Water soluble",

author = "Sven Hida and Roman, \{Paul J.\} and Bowden, \{Allen A.\} and Atwood, \{Jim D.\}",

year = "1998",

doi = "10.1080/00958979808230447",

language = "English",

volume = "43",

pages = "345--348",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "4",

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TY - JOUR

T1 - Synthesis of tri(m-sulfonatedphenyl)phosphine (TPPTS)

T2 - The importance of pH in the work-up

AU - Hida, Sven

AU - Roman, Paul J.

AU - Bowden, Allen A.

AU - Atwood, Jim D.

PY - 1998

Y1 - 1998

N2 - Controlling the pH during workup allows synthesis of TPPTS, P(m-C6H4SO3Na)3, without interference from the oxide. The recrystallized yield is 70% based on P(m-C6H4SO3Na)3·3H 2O from PPh3.

AB - Controlling the pH during workup allows synthesis of TPPTS, P(m-C6H4SO3Na)3, without interference from the oxide. The recrystallized yield is 70% based on P(m-C6H4SO3Na)3·3H 2O from PPh3.

KW - Sulfonated ligands

KW - TPPTS

KW - Water soluble

UR - https://www.scopus.com/pages/publications/0000403266

U2 - 10.1080/00958979808230447

DO - 10.1080/00958979808230447

M3 - Article

AN - SCOPUS:0000403266

SN - 0095-8972

VL - 43

SP - 345

EP - 348

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 4

ER -

Synthesis of tri(m-sulfonatedphenyl)phosphine (TPPTS): The importance of pH in the work-up

Abstract

Keywords

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