Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor

Gurijala V. Reddy; Rakesh K. Jain; Balwinder S. Bhatti; Khushi L. Matta

doi:10.1016/0008-6215(94)00153-7

Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor

Gurijala V. Reddy
, Rakesh K. Jain
, Balwinder S. Bhatti
, Khushi L. Matta

Department of Chemical and Biological Engineering

Roswell Park Cancer Institute

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Synthesis of two trisaccharides and a tetrasaccharide, namely, α-Gal-(1 → 3)- β-Gal-(1 → 3)-GlcNAc-β-OBn (6), α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc- β-OBn (9) and α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc-β-(1 → 6)-GalNAc- α-OBn (19) was accomplished through development and utilization of a key α- galactosyl donor, methyl 2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio-β-d- galactopyranoside (1).

Original language	English
Pages (from-to)	67-77
Number of pages	11
Journal	Carbohydrate Research
Volume	263
Issue number	1
DOIs	https://doi.org/10.1016/0008-6215(94)00153-7
State	Published - Oct 3 1994

Keywords

Glycosyl donor
Synthesis of α-d-galactopyranosyl-linked oligosaccharides

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Reddy, G. V., Jain, R. K., Bhatti, B. S., & Matta, K. L. (1994). Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor. Carbohydrate Research, 263(1), 67-77. https://doi.org/10.1016/0008-6215(94)00153-7

@article{e2ee47b2d0034c6c915ecbec0e76d62e,

title = "Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor",

abstract = "Synthesis of two trisaccharides and a tetrasaccharide, namely, α-Gal-(1 → 3)- β-Gal-(1 → 3)-GlcNAc-β-OBn (6), α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc- β-OBn (9) and α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc-β-(1 → 6)-GalNAc- α-OBn (19) was accomplished through development and utilization of a key α- galactosyl donor, methyl 2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio-β-d- galactopyranoside (1).",

keywords = "Glycosyl donor, Synthesis of α-d-galactopyranosyl-linked oligosaccharides",

author = "Reddy, \{Gurijala V.\} and Jain, \{Rakesh K.\} and Bhatti, \{Balwinder S.\} and Matta, \{Khushi L.\}",

year = "1994",

month = oct,

day = "3",

doi = "10.1016/0008-6215(94)00153-7",

language = "English",

volume = "263",

pages = "67--77",

journal = "Carbohydrate Research",

issn = "0008-6215",

publisher = "Elsevier Ltd",

number = "1",

}

Reddy, GV, Jain, RK, Bhatti, BS & Matta, KL 1994, 'Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor', Carbohydrate Research, vol. 263, no. 1, pp. 67-77. https://doi.org/10.1016/0008-6215(94)00153-7

Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor. / Reddy, Gurijala V.; Jain, Rakesh K.; Bhatti, Balwinder S. et al.
In: Carbohydrate Research, Vol. 263, No. 1, 03.10.1994, p. 67-77.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor

AU - Reddy, Gurijala V.

AU - Jain, Rakesh K.

AU - Bhatti, Balwinder S.

AU - Matta, Khushi L.

PY - 1994/10/3

Y1 - 1994/10/3

N2 - Synthesis of two trisaccharides and a tetrasaccharide, namely, α-Gal-(1 → 3)- β-Gal-(1 → 3)-GlcNAc-β-OBn (6), α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc- β-OBn (9) and α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc-β-(1 → 6)-GalNAc- α-OBn (19) was accomplished through development and utilization of a key α- galactosyl donor, methyl 2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio-β-d- galactopyranoside (1).

AB - Synthesis of two trisaccharides and a tetrasaccharide, namely, α-Gal-(1 → 3)- β-Gal-(1 → 3)-GlcNAc-β-OBn (6), α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc- β-OBn (9) and α-Gal-(1 → 3)-β-Gal-(1 → 4)-GlcNAc-β-(1 → 6)-GalNAc- α-OBn (19) was accomplished through development and utilization of a key α- galactosyl donor, methyl 2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio-β-d- galactopyranoside (1).

KW - Glycosyl donor

KW - Synthesis of α-d-galactopyranosyl-linked oligosaccharides

UR - https://www.scopus.com/pages/publications/0028763152

U2 - 10.1016/0008-6215(94)00153-7

DO - 10.1016/0008-6215(94)00153-7

M3 - Article

C2 - 7982231

AN - SCOPUS:0028763152

SN - 0008-6215

VL - 263

SP - 67

EP - 77

JO - Carbohydrate Research

JF - Carbohydrate Research

IS - 1

ER -

Synthesis of α-d-galactopyranosyl-linked oligosaccharides containing the α-Gal → β-Gal → GlcNAc sequence employing methyl-2,3,4,6-tetra-O-(4-methoxybenzyl)-1-thio- β-d-galactopyranoside as an efficient glycosyl donor

Abstract

Keywords

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