Synthesis, characterization of tert-butyl methacrylate and its anionic polymerization

Jiebin Pang; Guantai Jin; Yuanxue Hou; Hongmin Zhang; Chong Cheng

Synthesis, characterization of tert-butyl methacrylate and its anionic polymerization

Jiebin Pang
, Guantai Jin
, Yuanxue Hou
, Hongmin Zhang
, Chong Cheng

Department of Chemical and Biological Engineering

Beijing University of Chemical Technology

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Tert-butyl α-methacrylate (TBMA) was synthesized by alcoholysis reaction of α-methylacryloyl chloride with tert-butyl alcohol. It was characterized by GC/MS, IR and NMR. Furthermore, through the study of anionic polymerization of TBMA, it was found that TBMA can undergo living anionic polymerization at 10°C using 1,1-diphenyl hexyl lithium (DPHL) as initiator.

Original language	English
Pages (from-to)	18-19
Number of pages	2
Journal	Beijing Huagong Daxue Xuebao (Ziran Kexueban)/Journal of Beijing University of Chemical Technology
Volume	25
Issue number	3
State	Published - 1998

Keywords

Anionic polymerization
Characterization
Synthesis
Tert-butyl α-methacrylate

Cite this

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title = "Synthesis, characterization of tert-butyl methacrylate and its anionic polymerization",

abstract = "Tert-butyl α-methacrylate (TBMA) was synthesized by alcoholysis reaction of α-methylacryloyl chloride with tert-butyl alcohol. It was characterized by GC/MS, IR and NMR. Furthermore, through the study of anionic polymerization of TBMA, it was found that TBMA can undergo living anionic polymerization at 10°C using 1,1-diphenyl hexyl lithium (DPHL) as initiator.",

keywords = "Anionic polymerization, Characterization, Synthesis, Tert-butyl α-methacrylate",

author = "Jiebin Pang and Guantai Jin and Yuanxue Hou and Hongmin Zhang and Chong Cheng",

year = "1998",

language = "English",

volume = "25",

pages = "18--19",

journal = "Beijing Huagong Daxue Xuebao (Ziran Kexueban)/Journal of Beijing University of Chemical Technology",

issn = "1007-2640",

publisher = "Beijing University of Chemical Technology",

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TY - JOUR

T1 - Synthesis, characterization of tert-butyl methacrylate and its anionic polymerization

AU - Pang, Jiebin

AU - Jin, Guantai

AU - Hou, Yuanxue

AU - Zhang, Hongmin

AU - Cheng, Chong

PY - 1998

Y1 - 1998

N2 - Tert-butyl α-methacrylate (TBMA) was synthesized by alcoholysis reaction of α-methylacryloyl chloride with tert-butyl alcohol. It was characterized by GC/MS, IR and NMR. Furthermore, through the study of anionic polymerization of TBMA, it was found that TBMA can undergo living anionic polymerization at 10°C using 1,1-diphenyl hexyl lithium (DPHL) as initiator.

AB - Tert-butyl α-methacrylate (TBMA) was synthesized by alcoholysis reaction of α-methylacryloyl chloride with tert-butyl alcohol. It was characterized by GC/MS, IR and NMR. Furthermore, through the study of anionic polymerization of TBMA, it was found that TBMA can undergo living anionic polymerization at 10°C using 1,1-diphenyl hexyl lithium (DPHL) as initiator.

KW - Anionic polymerization

KW - Characterization

KW - Synthesis

KW - Tert-butyl α-methacrylate

UR - https://www.scopus.com/pages/publications/0346276463

M3 - Article

AN - SCOPUS:0346276463

SN - 1007-2640

VL - 25

SP - 18

EP - 19

JO - Beijing Huagong Daxue Xuebao (Ziran Kexueban)/Journal of Beijing University of Chemical Technology

JF - Beijing Huagong Daxue Xuebao (Ziran Kexueban)/Journal of Beijing University of Chemical Technology

IS - 3

ER -

Synthesis, characterization of tert-butyl methacrylate and its anionic polymerization

Abstract

Keywords

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