Surface spectroscopic studies of polymer surfaces and interfaces: 2. Poly(tetramethyl-P-silphenylenesiloxane poly(dimethylsiloxane) block copolymers

Robert L. Schmitt; Joseph A. Gardella; Joseph H. Magill; Roland L. Chin

doi:10.1016/0032-3861(87)90342-9

Surface spectroscopic studies of polymer surfaces and interfaces: 2. Poly(tetramethyl-P-silphenylenesiloxane poly(dimethylsiloxane) block copolymers

Robert L. Schmitt
, Joseph A. Gardella
, Joseph H. Magill
, Roland L. Chin

Chemistry

SUNY Buffalo
University of Pittsburgh
Honeywell

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The surface region of a series of poly(tetramethyl-p-silphenylenesiloxane) poly(dimethylsiloxane) block copolymers was investigated using X-ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infra-red spectroscopy. Analysis of the results shows the surface region to be equivalent to the bulk composition for all but one sample. This indicates that for all but the most crystalline samples the surface region comprises a relatively thick layer of non-crystalline amorphous domains.

Original language	English
Pages (from-to)	1462-1466
Number of pages	5
Journal	Polymer
Volume	28
Issue number	9
DOIs	https://doi.org/10.1016/0032-3861(87)90342-9
State	Published - Aug 1987

Keywords

block copolymer
crystallinity
e.s.c.a.
surface analysis

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10.1016/0032-3861(87)90342-9

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title = "Surface spectroscopic studies of polymer surfaces and interfaces: 2. Poly(tetramethyl-P-silphenylenesiloxane poly(dimethylsiloxane) block copolymers",

abstract = "The surface region of a series of poly(tetramethyl-p-silphenylenesiloxane) poly(dimethylsiloxane) block copolymers was investigated using X-ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infra-red spectroscopy. Analysis of the results shows the surface region to be equivalent to the bulk composition for all but one sample. This indicates that for all but the most crystalline samples the surface region comprises a relatively thick layer of non-crystalline amorphous domains.",

keywords = "block copolymer, crystallinity, e.s.c.a., surface analysis",

author = "Schmitt, \{Robert L.\} and Gardella, \{Joseph A.\} and Magill, \{Joseph H.\} and Chin, \{Roland L.\}",

year = "1987",

month = aug,

doi = "10.1016/0032-3861(87)90342-9",

language = "English",

volume = "28",

pages = "1462--1466",

journal = "Polymer",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Surface spectroscopic studies of polymer surfaces and interfaces

T2 - 2. Poly(tetramethyl-P-silphenylenesiloxane poly(dimethylsiloxane) block copolymers

AU - Schmitt, Robert L.

AU - Gardella, Joseph A.

AU - Magill, Joseph H.

AU - Chin, Roland L.

PY - 1987/8

Y1 - 1987/8

N2 - The surface region of a series of poly(tetramethyl-p-silphenylenesiloxane) poly(dimethylsiloxane) block copolymers was investigated using X-ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infra-red spectroscopy. Analysis of the results shows the surface region to be equivalent to the bulk composition for all but one sample. This indicates that for all but the most crystalline samples the surface region comprises a relatively thick layer of non-crystalline amorphous domains.

AB - The surface region of a series of poly(tetramethyl-p-silphenylenesiloxane) poly(dimethylsiloxane) block copolymers was investigated using X-ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infra-red spectroscopy. Analysis of the results shows the surface region to be equivalent to the bulk composition for all but one sample. This indicates that for all but the most crystalline samples the surface region comprises a relatively thick layer of non-crystalline amorphous domains.

KW - block copolymer

KW - crystallinity

KW - e.s.c.a.

KW - surface analysis

UR - https://www.scopus.com/pages/publications/0023399246

U2 - 10.1016/0032-3861(87)90342-9

DO - 10.1016/0032-3861(87)90342-9

M3 - Article

AN - SCOPUS:0023399246

SN - 0032-3861

VL - 28

SP - 1462

EP - 1466

JO - Polymer

JF - Polymer

IS - 9

ER -

Surface spectroscopic studies of polymer surfaces and interfaces: 2. Poly(tetramethyl-P-silphenylenesiloxane poly(dimethylsiloxane) block copolymers

Abstract

Keywords

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