Surface composition of fluorinated poly(amide urethane) block copolymers by electron spectroscopy for chemical analysis

Hengzhong Zhuang; Kacey Gribbin Marra; Tai Ho; Toby M. Chapman; Joseph A. Gardella

doi:10.1021/ma950860d

Surface composition of fluorinated poly(amide urethane) block copolymers by electron spectroscopy for chemical analysis

Hengzhong Zhuang
, Kacey Gribbin Marra
, Tai Ho
, Toby M. Chapman
, Joseph A. Gardella

Chemistry

SUNY Buffalo
University of Pittsburgh
Virginia Polytechnic Institute and State University

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The surface composition and near-surface depth profiles of annealed films of poly(amide urethane) block copolymers were measured using angle-dependent electron spectroscopy for chemical analysis (ESCA). Segregation of the fluorinated polyamide soft segment to the surface was detected and quantified. The poly(amide urethane)s were made from amine-terminated polyamides with N-alkylated fluorinated side chains as well as fluorinated backbones, methylenebis(cyclohexandiyl diisocyanate) (H₁₂-MDI), and butanediol.¹ The resulting copolymers display extremely low surface energy. A deconvolution program was utilized to obtain composition-depth profiles and to confirm phase segregation.

Original language	English
Pages (from-to)	1660-1665
Number of pages	6
Journal	Macromolecules
Volume	29
Issue number	5
DOIs	https://doi.org/10.1021/ma950860d
State	Published - Feb 26 1996

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title = "Surface composition of fluorinated poly(amide urethane) block copolymers by electron spectroscopy for chemical analysis",

abstract = "The surface composition and near-surface depth profiles of annealed films of poly(amide urethane) block copolymers were measured using angle-dependent electron spectroscopy for chemical analysis (ESCA). Segregation of the fluorinated polyamide soft segment to the surface was detected and quantified. The poly(amide urethane)s were made from amine-terminated polyamides with N-alkylated fluorinated side chains as well as fluorinated backbones, methylenebis(cyclohexandiyl diisocyanate) (H12-MDI), and butanediol.1 The resulting copolymers display extremely low surface energy. A deconvolution program was utilized to obtain composition-depth profiles and to confirm phase segregation.",

author = "Hengzhong Zhuang and Marra, \{Kacey Gribbin\} and Tai Ho and Chapman, \{Toby M.\} and Gardella, \{Joseph A.\}",

year = "1996",

month = feb,

day = "26",

doi = "10.1021/ma950860d",

language = "English",

volume = "29",

pages = "1660--1665",

journal = "Macromolecules",

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T1 - Surface composition of fluorinated poly(amide urethane) block copolymers by electron spectroscopy for chemical analysis

AU - Zhuang, Hengzhong

AU - Marra, Kacey Gribbin

AU - Ho, Tai

AU - Chapman, Toby M.

AU - Gardella, Joseph A.

PY - 1996/2/26

Y1 - 1996/2/26

N2 - The surface composition and near-surface depth profiles of annealed films of poly(amide urethane) block copolymers were measured using angle-dependent electron spectroscopy for chemical analysis (ESCA). Segregation of the fluorinated polyamide soft segment to the surface was detected and quantified. The poly(amide urethane)s were made from amine-terminated polyamides with N-alkylated fluorinated side chains as well as fluorinated backbones, methylenebis(cyclohexandiyl diisocyanate) (H12-MDI), and butanediol.1 The resulting copolymers display extremely low surface energy. A deconvolution program was utilized to obtain composition-depth profiles and to confirm phase segregation.

AB - The surface composition and near-surface depth profiles of annealed films of poly(amide urethane) block copolymers were measured using angle-dependent electron spectroscopy for chemical analysis (ESCA). Segregation of the fluorinated polyamide soft segment to the surface was detected and quantified. The poly(amide urethane)s were made from amine-terminated polyamides with N-alkylated fluorinated side chains as well as fluorinated backbones, methylenebis(cyclohexandiyl diisocyanate) (H12-MDI), and butanediol.1 The resulting copolymers display extremely low surface energy. A deconvolution program was utilized to obtain composition-depth profiles and to confirm phase segregation.

UR - https://www.scopus.com/pages/publications/0001186814

U2 - 10.1021/ma950860d

DO - 10.1021/ma950860d

M3 - Article

AN - SCOPUS:0001186814

SN - 0024-9297

VL - 29

SP - 1660

EP - 1665

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

Surface composition of fluorinated poly(amide urethane) block copolymers by electron spectroscopy for chemical analysis

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