Surface analysis of poly(acrylonitrile-co-methyl methacrylate) multicomponent polymers by a multi-technique approach

Philip L. Kumler; Joseph A. Gardella

Surface analysis of poly(acrylonitrile-co-methyl methacrylate) multicomponent polymers by a multi-technique approach

Philip L. Kumler
, Joseph A. Gardella

Chemistry

State University of New York at Fredonia

Research output: Contribution to journal › Conference article › peer-review

Abstract

An extensive series of acrylonitrile-methyl methacrylate (AN-MMA) copolymers has previously been prepared; the bulk properties of this series were evaluated by differential scanning calorimetry (DSC) and transmission IR spectroscopy. The series includes statistical copolymers and 'blocky' copolymers (average PAN sequence lengths >100). The entire series, including the addition of several AN-MMA block copolymers, has now been examined by various surface sensitive techniques, primarily angle-resolved ESCA and attentuated total reflectance IR (ATR-FTIR). In general, the surface composition of the series differed from that of the bulk phase and these variations provide insight into the factors controlling surface segregation in multicomponent polymers.

Original language	English
Pages (from-to)	870
Number of pages	1
Journal	Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering
Volume	62
State	Published - 1990
Event	Proceedings of the ACS Division of Polymeric Materials: Science and Engineering - Boston, MA, USA Duration: Apr 1 1990 → Apr 1 1990

Cite this

@article{28c59796d94240aca83fef433aef8b71,

title = "Surface analysis of poly(acrylonitrile-co-methyl methacrylate) multicomponent polymers by a multi-technique approach",

abstract = "An extensive series of acrylonitrile-methyl methacrylate (AN-MMA) copolymers has previously been prepared; the bulk properties of this series were evaluated by differential scanning calorimetry (DSC) and transmission IR spectroscopy. The series includes statistical copolymers and 'blocky' copolymers (average PAN sequence lengths >100). The entire series, including the addition of several AN-MMA block copolymers, has now been examined by various surface sensitive techniques, primarily angle-resolved ESCA and attentuated total reflectance IR (ATR-FTIR). In general, the surface composition of the series differed from that of the bulk phase and these variations provide insight into the factors controlling surface segregation in multicomponent polymers.",

author = "Kumler, \{Philip L.\} and Gardella, \{Joseph A.\}",

year = "1990",

language = "English",

volume = "62",

pages = "870",

journal = "Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering",

issn = "0743-0515",

note = "Proceedings of the ACS Division of Polymeric Materials: Science and Engineering ; Conference date: 01-04-1990 Through 01-04-1990",

}

Surface analysis of poly(acrylonitrile-co-methyl methacrylate) multicomponent polymers by a multi-technique approach. / Kumler, Philip L.; Gardella, Joseph A.
In: Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, Vol. 62, 1990, p. 870.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Surface analysis of poly(acrylonitrile-co-methyl methacrylate) multicomponent polymers by a multi-technique approach

AU - Kumler, Philip L.

AU - Gardella, Joseph A.

PY - 1990

Y1 - 1990

N2 - An extensive series of acrylonitrile-methyl methacrylate (AN-MMA) copolymers has previously been prepared; the bulk properties of this series were evaluated by differential scanning calorimetry (DSC) and transmission IR spectroscopy. The series includes statistical copolymers and 'blocky' copolymers (average PAN sequence lengths >100). The entire series, including the addition of several AN-MMA block copolymers, has now been examined by various surface sensitive techniques, primarily angle-resolved ESCA and attentuated total reflectance IR (ATR-FTIR). In general, the surface composition of the series differed from that of the bulk phase and these variations provide insight into the factors controlling surface segregation in multicomponent polymers.

AB - An extensive series of acrylonitrile-methyl methacrylate (AN-MMA) copolymers has previously been prepared; the bulk properties of this series were evaluated by differential scanning calorimetry (DSC) and transmission IR spectroscopy. The series includes statistical copolymers and 'blocky' copolymers (average PAN sequence lengths >100). The entire series, including the addition of several AN-MMA block copolymers, has now been examined by various surface sensitive techniques, primarily angle-resolved ESCA and attentuated total reflectance IR (ATR-FTIR). In general, the surface composition of the series differed from that of the bulk phase and these variations provide insight into the factors controlling surface segregation in multicomponent polymers.

UR - https://www.scopus.com/pages/publications/0025238336

M3 - Conference article

AN - SCOPUS:0025238336

SN - 0743-0515

VL - 62

SP - 870

JO - Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering

JF - Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering

T2 - Proceedings of the ACS Division of Polymeric Materials: Science and Engineering

Y2 - 1 April 1990 through 1 April 1990

ER -

Surface analysis of poly(acrylonitrile-co-methyl methacrylate) multicomponent polymers by a multi-technique approach

Abstract

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