Structure of the iodine columns in iodinated nylon‐6

Ryszard Burzynski; Paras N. Prasad; N. Sanjeeva Murthy

doi:10.1002/polb.1986.180240114

Structure of the iodine columns in iodinated nylon‐6

Ryszard Burzynski
, Paras N. Prasad
, N. Sanjeeva Murthy

Chemistry

SUNY Buffalo
Honeywell

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

A study of iodine‐complexed nylon 6 films by polarized resonance Raman spectra shows the presence of both I₃⁻ and I₅⁻ species, the latter most likely in the form of an I₂/I₃⁻ complex. Polarization characteristics of the Raman spectra show that the I₂/I₃ units are orinted along the polymer chain and the I₃⁻ ions are perpendicular to the chain axis. The I₂/I₃⁻ units are in a more stable moiety than the I₃⁻ species. These Raman results are consistent with the x‐ray diffraction data.

Original language	English
Pages (from-to)	133-141
Number of pages	9
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	24
Issue number	1
DOIs	https://doi.org/10.1002/polb.1986.180240114
State	Published - Jan 1986

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title = "Structure of the iodine columns in iodinated nylon‐6",

abstract = "A study of iodine‐complexed nylon 6 films by polarized resonance Raman spectra shows the presence of both I3− and I5− species, the latter most likely in the form of an I2/I3− complex. Polarization characteristics of the Raman spectra show that the I2/I3 units are orinted along the polymer chain and the I3− ions are perpendicular to the chain axis. The I2/I3− units are in a more stable moiety than the I3− species. These Raman results are consistent with the x‐ray diffraction data.",

author = "Ryszard Burzynski and Prasad, \{Paras N.\} and Murthy, \{N. Sanjeeva\}",

year = "1986",

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doi = "10.1002/polb.1986.180240114",

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N2 - A study of iodine‐complexed nylon 6 films by polarized resonance Raman spectra shows the presence of both I3− and I5− species, the latter most likely in the form of an I2/I3− complex. Polarization characteristics of the Raman spectra show that the I2/I3 units are orinted along the polymer chain and the I3− ions are perpendicular to the chain axis. The I2/I3− units are in a more stable moiety than the I3− species. These Raman results are consistent with the x‐ray diffraction data.

AB - A study of iodine‐complexed nylon 6 films by polarized resonance Raman spectra shows the presence of both I3− and I5− species, the latter most likely in the form of an I2/I3− complex. Polarization characteristics of the Raman spectra show that the I2/I3 units are orinted along the polymer chain and the I3− ions are perpendicular to the chain axis. The I2/I3− units are in a more stable moiety than the I3− species. These Raman results are consistent with the x‐ray diffraction data.

UR - https://www.scopus.com/pages/publications/0022496193

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DO - 10.1002/polb.1986.180240114

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AN - SCOPUS:0022496193

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SP - 133

EP - 141

JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

IS - 1

ER -

Structure of the iodine columns in iodinated nylon‐6

Abstract

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