Stereochemistry of 14, 22-Ethers Formed by Cyclization of Δ7-22-Hydroxy Steroids

D. John Aberhart; Eliahu Caspi; Charles M. Weeks; William L. Duax

doi:10.1021/jo01315a018

Stereochemistry of 14, 22-Ethers Formed by Cyclization of Δ⁷-22-Hydroxy Steroids

D. John Aberhart
, Eliahu Caspi
, Charles M. Weeks
, William L. Duax

Department of Structural Biology

University of Massachusetts Medical School
Hauptman-Woodward Medical Research Institute, Inc.

Research output: Contribution to journal › Article › peer-review

Abstract

The 14, 22-ether 2c produced by mild acid treatment of 3β-benzoyloxy-23, 24-bisnor-5a-chol-7-en-22-ol (1a) is shown by X-ray crystallography to have the 8β(H),14β configuration.

Original language	English
Pages (from-to)	75-77
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	44
Issue number	1
DOIs	https://doi.org/10.1021/jo01315a018
State	Published - Feb 1 1979

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@article{03ad9578e11f4c95b65c208c1a8f6385,

title = "Stereochemistry of 14, 22-Ethers Formed by Cyclization of Δ7-22-Hydroxy Steroids",

abstract = "The 14, 22-ether 2c produced by mild acid treatment of 3β-benzoyloxy-23, 24-bisnor-5a-chol-7-en-22-ol (1a) is shown by X-ray crystallography to have the 8β(H),14β configuration.",

author = "Aberhart, \{D. John\} and Eliahu Caspi and Weeks, \{Charles M.\} and Duax, \{William L.\}",

year = "1979",

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doi = "10.1021/jo01315a018",

language = "English",

volume = "44",

pages = "75--77",

journal = "Journal of Organic Chemistry",

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publisher = "American Chemical Society",

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T1 - Stereochemistry of 14, 22-Ethers Formed by Cyclization of Δ7-22-Hydroxy Steroids

AU - Aberhart, D. John

AU - Caspi, Eliahu

AU - Weeks, Charles M.

AU - Duax, William L.

PY - 1979/2/1

Y1 - 1979/2/1

N2 - The 14, 22-ether 2c produced by mild acid treatment of 3β-benzoyloxy-23, 24-bisnor-5a-chol-7-en-22-ol (1a) is shown by X-ray crystallography to have the 8β(H),14β configuration.

AB - The 14, 22-ether 2c produced by mild acid treatment of 3β-benzoyloxy-23, 24-bisnor-5a-chol-7-en-22-ol (1a) is shown by X-ray crystallography to have the 8β(H),14β configuration.

UR - https://www.scopus.com/pages/publications/0018418765

U2 - 10.1021/jo01315a018

DO - 10.1021/jo01315a018

M3 - Article

AN - SCOPUS:0018418765

SN - 0022-3263

VL - 44

SP - 75

EP - 77

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 1

ER -

Stereochemistry of 14, 22-Ethers Formed by Cyclization of Δ⁷-22-Hydroxy Steroids

Abstract

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