Stark and hyperfine properties of oxygen difluoride

Robert L. DeLeon; Diana Prichard; J. S. Muenter

doi:10.1063/1.449758

Stark and hyperfine properties of oxygen difluoride

Robert L. DeLeon
, Diana Prichard
, J. S. Muenter

Center for Computational Research

University of Rochester

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Radio frequency transitions within six different rotational levels of oxygen difluoride have been observed in the presence of external electric fields. These data were analyzed in terms of the dipole moment, polarizability anisotropics, spin rotation, and spin-spin interactions:μ = 0.308 18(3) D, α_aa - α_bb = 1.389(8) Å³, α_aa - α_cc = 1.883(10) Å³, M_aa = 59.60(7) kHz, M_bb = 25.05(11) kHz, M_cc = 51.39(8) kHz, and 〈1/R³〉 = 0.0941(5) Å^-3.

Original language	English
Pages (from-to)	4962-4966
Number of pages	5
Journal	Journal of Chemical Physics
Volume	83
Issue number	10
DOIs	https://doi.org/10.1063/1.449758
State	Published - 1985

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@article{b4226bcf36424518ba0df28042d6ebc9,

title = "Stark and hyperfine properties of oxygen difluoride",

abstract = "Radio frequency transitions within six different rotational levels of oxygen difluoride have been observed in the presence of external electric fields. These data were analyzed in terms of the dipole moment, polarizability anisotropics, spin rotation, and spin-spin interactions:μ = 0.308 18(3) D, αaa - αbb = 1.389(8) {\AA}3, αaa - αcc = 1.883(10) {\AA}3, Maa = 59.60(7) kHz, Mbb = 25.05(11) kHz, Mcc = 51.39(8) kHz, and 〈1/R3〉 = 0.0941(5) {\AA}-3.",

author = "DeLeon, \{Robert L.\} and Diana Prichard and Muenter, \{J. S.\}",

year = "1985",

doi = "10.1063/1.449758",

language = "English",

volume = "83",

pages = "4962--4966",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "10",

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T1 - Stark and hyperfine properties of oxygen difluoride

AU - DeLeon, Robert L.

AU - Prichard, Diana

AU - Muenter, J. S.

PY - 1985

Y1 - 1985

N2 - Radio frequency transitions within six different rotational levels of oxygen difluoride have been observed in the presence of external electric fields. These data were analyzed in terms of the dipole moment, polarizability anisotropics, spin rotation, and spin-spin interactions:μ = 0.308 18(3) D, αaa - αbb = 1.389(8) Å3, αaa - αcc = 1.883(10) Å3, Maa = 59.60(7) kHz, Mbb = 25.05(11) kHz, Mcc = 51.39(8) kHz, and 〈1/R3〉 = 0.0941(5) Å-3.

AB - Radio frequency transitions within six different rotational levels of oxygen difluoride have been observed in the presence of external electric fields. These data were analyzed in terms of the dipole moment, polarizability anisotropics, spin rotation, and spin-spin interactions:μ = 0.308 18(3) D, αaa - αbb = 1.389(8) Å3, αaa - αcc = 1.883(10) Å3, Maa = 59.60(7) kHz, Mbb = 25.05(11) kHz, Mcc = 51.39(8) kHz, and 〈1/R3〉 = 0.0941(5) Å-3.

UR - https://www.scopus.com/pages/publications/0006174940

U2 - 10.1063/1.449758

DO - 10.1063/1.449758

M3 - Article

AN - SCOPUS:0006174940

SN - 0021-9606

VL - 83

SP - 4962

EP - 4966

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

ER -

Stark and hyperfine properties of oxygen difluoride

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