Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites

Hsinhan Tsai; Wanyi Nie; Jean Christophe Blancon; Constantinos C. Stoumpos; Chan Myae Myae Soe; Jinkyoung Yoo; Jared Crochet; Sergei Tretiak; Jacky Even; Aditya Sadhanala; Giovanni Azzellino; Roberto Brenes; Pulickel M. Ajayan; Vladimir Bulović; Samuel D. Stranks; Richard H. Friend; Mercouri G. Kanatzidis; Aditya D. Mohite

doi:10.1002/adma.201704217

Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites

Hsinhan Tsai
, Wanyi Nie
, Jean Christophe Blancon
, Constantinos C. Stoumpos
, Chan Myae Myae Soe
, Jinkyoung Yoo
, Jared Crochet
, Sergei Tretiak
, Jacky Even
, Aditya Sadhanala
, Giovanni Azzellino
, Roberto Brenes
, Pulickel M. Ajayan
, Vladimir Bulović
, Samuel D. Stranks
, Richard H. Friend
, Mercouri G. Kanatzidis
, Aditya D. Mohite

Los Alamos National Laboratory
Northwestern University
Institut FOTON - UMR 6082
University of Cambridge
Massachusetts Institute of Technology
Rice University

Research output: Contribution to journal › Article › peer-review

294 Scopus citations

Abstract

State-of-the-art light-emitting diodes (LEDs) are made from high-purity alloys of III–V semiconductors, but high fabrication cost has limited their widespread use for large area solid-state lighting. Here, efficient and stable LEDs processed from solution with tunable color enabled by using phase-pure 2D Ruddlesden–Popper (RP) halide perovskites with a formula (CH₃(CH₂)₃NH₃)₂(CH₃NH₃)_n ₋₁Pb_nI₃ _n ₊₁ are reported. By using vertically oriented thin films that facilitate efficient charge injection and transport, efficient electroluminescence with a radiance of 35 W Sr⁻¹ cm⁻² at 744 nm with an ultralow turn-on voltage of 1 V is obtained. Finally, operational stability tests suggest that phase purity is strongly correlated to stability. Phase-pure 2D perovskites exhibit >14 h of stable operation at peak operating conditions with no droop at current densities of several Amperes cm⁻² in comparison to mixtures of 2D/3D or 3D perovskites, which degrade within minutes.

Original language	English
Article number	1704217
Journal	Advanced Materials
Volume	30
Issue number	6
DOIs	https://doi.org/10.1002/adma.201704217
State	Published - Feb 8 2018

Keywords

LEDs
Ruddlesden–Popper layered perovskites
color tunability
crystal orientation

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10.1002/adma.201704217

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Tsai, H., Nie, W., Blancon, J. C., Stoumpos, C. C., Soe, C. M. M., Yoo, J., Crochet, J., Tretiak, S., Even, J., Sadhanala, A., Azzellino, G., Brenes, R., Ajayan, P. M., Bulović, V., Stranks, S. D., Friend, R. H., Kanatzidis, M. G., & Mohite, A. D. (2018). Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites. Advanced Materials, 30(6), Article 1704217. https://doi.org/10.1002/adma.201704217

@article{309d0b16da114d4386eed51cd18ef9ea,

title = "Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites",

abstract = "State-of-the-art light-emitting diodes (LEDs) are made from high-purity alloys of III–V semiconductors, but high fabrication cost has limited their widespread use for large area solid-state lighting. Here, efficient and stable LEDs processed from solution with tunable color enabled by using phase-pure 2D Ruddlesden–Popper (RP) halide perovskites with a formula (CH3(CH2)3NH3)2(CH3NH3)n −1PbnI3 n +1 are reported. By using vertically oriented thin films that facilitate efficient charge injection and transport, efficient electroluminescence with a radiance of 35 W Sr−1 cm−2 at 744 nm with an ultralow turn-on voltage of 1 V is obtained. Finally, operational stability tests suggest that phase purity is strongly correlated to stability. Phase-pure 2D perovskites exhibit >14 h of stable operation at peak operating conditions with no droop at current densities of several Amperes cm−2 in comparison to mixtures of 2D/3D or 3D perovskites, which degrade within minutes.",

keywords = "LEDs, Ruddlesden–Popper layered perovskites, color tunability, crystal orientation",

author = "Hsinhan Tsai and Wanyi Nie and Blancon, \{Jean Christophe\} and Stoumpos, \{Constantinos C.\} and Soe, \{Chan Myae Myae\} and Jinkyoung Yoo and Jared Crochet and Sergei Tretiak and Jacky Even and Aditya Sadhanala and Giovanni Azzellino and Roberto Brenes and Ajayan, \{Pulickel M.\} and Vladimir Bulovi{\'c} and Stranks, \{Samuel D.\} and Friend, \{Richard H.\} and Kanatzidis, \{Mercouri G.\} and Mohite, \{Aditya D.\}",

note = "Publisher Copyright: {\textcopyright} 2018 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = feb,

day = "8",

doi = "10.1002/adma.201704217",

language = "English",

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Tsai, H , Nie, W, Blancon, JC, Stoumpos, CC, Soe, CMM, Yoo, J, Crochet, J, Tretiak, S, Even, J, Sadhanala, A, Azzellino, G, Brenes, R, Ajayan, PM, Bulović, V, Stranks, SD, Friend, RH, Kanatzidis, MG & Mohite, AD 2018, 'Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites', Advanced Materials, vol. 30, no. 6, 1704217. https://doi.org/10.1002/adma.201704217

TY - JOUR

T1 - Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites

AU - Tsai, Hsinhan

AU - Nie, Wanyi

AU - Blancon, Jean Christophe

AU - Stoumpos, Constantinos C.

AU - Soe, Chan Myae Myae

AU - Yoo, Jinkyoung

AU - Crochet, Jared

AU - Tretiak, Sergei

AU - Even, Jacky

AU - Sadhanala, Aditya

AU - Azzellino, Giovanni

AU - Brenes, Roberto

AU - Ajayan, Pulickel M.

AU - Bulović, Vladimir

AU - Stranks, Samuel D.

AU - Friend, Richard H.

AU - Kanatzidis, Mercouri G.

AU - Mohite, Aditya D.

PY - 2018/2/8

Y1 - 2018/2/8

N2 - State-of-the-art light-emitting diodes (LEDs) are made from high-purity alloys of III–V semiconductors, but high fabrication cost has limited their widespread use for large area solid-state lighting. Here, efficient and stable LEDs processed from solution with tunable color enabled by using phase-pure 2D Ruddlesden–Popper (RP) halide perovskites with a formula (CH3(CH2)3NH3)2(CH3NH3)n −1PbnI3 n +1 are reported. By using vertically oriented thin films that facilitate efficient charge injection and transport, efficient electroluminescence with a radiance of 35 W Sr−1 cm−2 at 744 nm with an ultralow turn-on voltage of 1 V is obtained. Finally, operational stability tests suggest that phase purity is strongly correlated to stability. Phase-pure 2D perovskites exhibit >14 h of stable operation at peak operating conditions with no droop at current densities of several Amperes cm−2 in comparison to mixtures of 2D/3D or 3D perovskites, which degrade within minutes.

AB - State-of-the-art light-emitting diodes (LEDs) are made from high-purity alloys of III–V semiconductors, but high fabrication cost has limited their widespread use for large area solid-state lighting. Here, efficient and stable LEDs processed from solution with tunable color enabled by using phase-pure 2D Ruddlesden–Popper (RP) halide perovskites with a formula (CH3(CH2)3NH3)2(CH3NH3)n −1PbnI3 n +1 are reported. By using vertically oriented thin films that facilitate efficient charge injection and transport, efficient electroluminescence with a radiance of 35 W Sr−1 cm−2 at 744 nm with an ultralow turn-on voltage of 1 V is obtained. Finally, operational stability tests suggest that phase purity is strongly correlated to stability. Phase-pure 2D perovskites exhibit >14 h of stable operation at peak operating conditions with no droop at current densities of several Amperes cm−2 in comparison to mixtures of 2D/3D or 3D perovskites, which degrade within minutes.

KW - LEDs

KW - Ruddlesden–Popper layered perovskites

KW - color tunability

KW - crystal orientation

UR - https://www.scopus.com/pages/publications/85039997384

U2 - 10.1002/adma.201704217

DO - 10.1002/adma.201704217

M3 - Article

C2 - 29314326

AN - SCOPUS:85039997384

SN - 0935-9648

VL - 30

JO - Advanced Materials

JF - Advanced Materials

IS - 6

M1 - 1704217

ER -

Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden–Popper Layered Perovskites

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