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Solder joint grain boundary structure and diffusivity via molecular dynamics simulations

  • SUNY Buffalo

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Scopus citations

Abstract

We investigate the effect of various amounts of Ag and Cu solute atoms on the self-diffusivity of Sn in the (101) symmetric tilt βSn grain boundary. Using molecular dynamics (MD) simulations over a temperature range of 300K to 450K, we show that both Ag and Cu decrease the grain boundary self-diffusivity of Sn, as the amount of solute in the interface increases. Additionally, the presence of Ag at the grain boundary interface causes a greater reduction in the self-diffusivity of Sn when compared to Cu. We also analyze the solute effect on the diffusive width of the interface and find that low concentrations of both Ag and Cu shrink the width relative to the pure βSn interface.

Original languageEnglish
Title of host publicationProceedings of the 13th InterSociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems, ITherm 2012
Pages514-517
Number of pages4
DOIs
StatePublished - 2012
Event13th InterSociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems, ITherm 2012 - San Diego, CA, United States
Duration: May 30 2012Jun 1 2012

Publication series

NameInterSociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems, ITHERM
ISSN (Print)1936-3958

Conference

Conference13th InterSociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems, ITherm 2012
Country/TerritoryUnited States
CitySan Diego, CA
Period05/30/1206/1/12

Keywords

  • diffusivity
  • grain boundary diffusivity
  • lead-free solder alloy
  • Molecular dynamics
  • solute

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