Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes

Qing Zheng Yang; Daria Khvostichenko; John D. Atkinson; Roman Boulatov

doi:10.1039/b717858a

Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes

Qing Zheng Yang
, Daria Khvostichenko
, John D. Atkinson
, Roman Boulatov

Department of Civil, Structural & Environmental Engineering

University of Illinois at Urbana-Champaign

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

In weakly coordinating solvents Fe^II meso-(N-methylimidazol-2- yl)porphine 1Fe exists as a stable dimer (K_d = 50 ± 30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.

Original language	English
Pages (from-to)	963-965
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b717858a
State	Published - 2008

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10.1039/b717858a

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@article{d78cbf85516b4192b77ce70e735233bc,

title = "Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes",

abstract = "In weakly coordinating solvents FeII meso-(N-methylimidazol-2- yl)porphine 1Fe exists as a stable dimer (Kd = 50 ± 30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.",

author = "Yang, \{Qing Zheng\} and Daria Khvostichenko and Atkinson, \{John D.\} and Roman Boulatov",

year = "2008",

doi = "10.1039/b717858a",

language = "English",

pages = "963--965",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "8",

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TY - JOUR

T1 - Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes

AU - Yang, Qing Zheng

AU - Khvostichenko, Daria

AU - Atkinson, John D.

AU - Boulatov, Roman

PY - 2008

Y1 - 2008

N2 - In weakly coordinating solvents FeII meso-(N-methylimidazol-2- yl)porphine 1Fe exists as a stable dimer (Kd = 50 ± 30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.

AB - In weakly coordinating solvents FeII meso-(N-methylimidazol-2- yl)porphine 1Fe exists as a stable dimer (Kd = 50 ± 30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.

UR - https://www.scopus.com/pages/publications/39549083295

U2 - 10.1039/b717858a

DO - 10.1039/b717858a

M3 - Article

AN - SCOPUS:39549083295

SN - 1359-7345

SP - 963

EP - 965

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes

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