Selectivity in C-O Bond Formation: Reaction of Acid Chlorides and Methyl Iodide with trans-MeOIr(CO)(PPh3)2

Karen A. Bernard; Jim D. Atwood

doi:10.1021/om00148a037

Selectivity in C-O Bond Formation: Reaction of Acid Chlorides and Methyl Iodide with trans-MeOIr(CO)(PPh₃)₂

Karen A. Bernard
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Reactions of RX (RX = Mel, CH₃C(0)CI, C_eH₅C(0)CI, and C_eH₅CH₂C(0)CI) with trans -MeOIr(CO)-(PPh₃)₂have been examined. In each case, an adduct is formed, RIr(OMeXCOXPPh₃)₂X, which is stable for R = Me. For the acid chlorides, this adduct eliminates ester, forming Ir(COXPPh₃)₂CI. Thus the carbon-oxygen bond leading to ester products is formed more readily than the carbon-oxygen bond leading to dimethyl ether.

Original language	English
Pages (from-to)	1133-1134
Number of pages	2
Journal	Organometallics
Volume	6
Issue number	5
DOIs	https://doi.org/10.1021/om00148a037
State	Published - May 1 1987

Access to Document

10.1021/om00148a037

Cite this

@article{806961c3641340348395a3c3ff49d791,

title = "Selectivity in C-O Bond Formation: Reaction of Acid Chlorides and Methyl Iodide with trans-MeOIr(CO)(PPh3)2",

abstract = "Reactions of RX (RX = Mel, CH3C(0)CI, CeH5C(0)CI, and CeH5CH2C(0)CI) with trans -MeOIr(CO)-(PPh3)2have been examined. In each case, an adduct is formed, RIr(OMeXCOXPPh3)2X, which is stable for R = Me. For the acid chlorides, this adduct eliminates ester, forming Ir(COXPPh3)2CI. Thus the carbon-oxygen bond leading to ester products is formed more readily than the carbon-oxygen bond leading to dimethyl ether.",

author = "Bernard, \{Karen A.\} and Atwood, \{Jim D.\}",

year = "1987",

month = may,

day = "1",

doi = "10.1021/om00148a037",

language = "English",

volume = "6",

pages = "1133--1134",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Selectivity in C-O Bond Formation

T2 - Reaction of Acid Chlorides and Methyl Iodide with trans-MeOIr(CO)(PPh3)2

AU - Bernard, Karen A.

AU - Atwood, Jim D.

PY - 1987/5/1

Y1 - 1987/5/1

N2 - Reactions of RX (RX = Mel, CH3C(0)CI, CeH5C(0)CI, and CeH5CH2C(0)CI) with trans -MeOIr(CO)-(PPh3)2have been examined. In each case, an adduct is formed, RIr(OMeXCOXPPh3)2X, which is stable for R = Me. For the acid chlorides, this adduct eliminates ester, forming Ir(COXPPh3)2CI. Thus the carbon-oxygen bond leading to ester products is formed more readily than the carbon-oxygen bond leading to dimethyl ether.

AB - Reactions of RX (RX = Mel, CH3C(0)CI, CeH5C(0)CI, and CeH5CH2C(0)CI) with trans -MeOIr(CO)-(PPh3)2have been examined. In each case, an adduct is formed, RIr(OMeXCOXPPh3)2X, which is stable for R = Me. For the acid chlorides, this adduct eliminates ester, forming Ir(COXPPh3)2CI. Thus the carbon-oxygen bond leading to ester products is formed more readily than the carbon-oxygen bond leading to dimethyl ether.

UR - https://www.scopus.com/pages/publications/0003593047

U2 - 10.1021/om00148a037

DO - 10.1021/om00148a037

M3 - Article

AN - SCOPUS:0003593047

SN - 0276-7333

VL - 6

SP - 1133

EP - 1134

JO - Organometallics

JF - Organometallics

IS - 5

ER -

Selectivity in C-O Bond Formation: Reaction of Acid Chlorides and Methyl Iodide with trans-MeOIr(CO)(PPh₃)₂

Abstract

Access to Document

Other files and links

Fingerprint

Cite this