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REVERSIBLE AND METASTABLE CHANGES IN THE RAMAN SPECTRUM OF GeS2 GLASS INDUCED BY COMPRESSION.

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Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

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Abstract

Cryobaric Raman measurements are reported for amorphous (a-) GeS//2 at 13K to 56 kbar. Hydrostaticity in a diamond-anvil cell is maintained by an argon pressure-transmitting medium. Pressure-induced peak shifts are fractionally small and reversible. However, peak broadenings are large (approximately 50-100%) and metastably retained, along with a newly emergent peak at 486cm** minus **1, after pressure release and dark-annealing. Evdence is found for pressure-assisted quasicrystallization at P equals 56 kbar. These results support a molecular model in which pressure squeezes out free (intermolecular) volume.

Original languageEnglish
Title of host publicationAIP Conference Proceedings
PublisherAIP
Pages457-464
Number of pages8
Edition120
ISBN (Print)0883183196, 9780883183199
DOIs
StatePublished - 1984

Publication series

NameAIP Conference Proceedings
Number120
ISSN (Print)0094-243X

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