Removal of ruthenium using a silica gel supported reagent

Jonathan M. French; Caley A. Caras; Steven T. Diver

doi:10.1021/ol402339e

Removal of ruthenium using a silica gel supported reagent

Jonathan M. French
, Caley A. Caras
, Steven T. Diver

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A solid-supported isocyanide ligand was developed to destroy active metathesis catalysts and to remove ruthenium byproducts from metathesis reactions. This method was able to significantly reduce the concentration of residual ruthenium from the organic products of several alkene and ene-yne metathesis reactions, under a variety of different conditions.

Original language	English
Pages (from-to)	5416-5419
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	21
DOIs	https://doi.org/10.1021/ol402339e
State	Published - Nov 1 2013

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10.1021/ol402339e

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title = "Removal of ruthenium using a silica gel supported reagent",

abstract = "A solid-supported isocyanide ligand was developed to destroy active metathesis catalysts and to remove ruthenium byproducts from metathesis reactions. This method was able to significantly reduce the concentration of residual ruthenium from the organic products of several alkene and ene-yne metathesis reactions, under a variety of different conditions.",

author = "French, \{Jonathan M.\} and Caras, \{Caley A.\} and Diver, \{Steven T.\}",

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AU - French, Jonathan M.

AU - Caras, Caley A.

AU - Diver, Steven T.

PY - 2013/11/1

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N2 - A solid-supported isocyanide ligand was developed to destroy active metathesis catalysts and to remove ruthenium byproducts from metathesis reactions. This method was able to significantly reduce the concentration of residual ruthenium from the organic products of several alkene and ene-yne metathesis reactions, under a variety of different conditions.

AB - A solid-supported isocyanide ligand was developed to destroy active metathesis catalysts and to remove ruthenium byproducts from metathesis reactions. This method was able to significantly reduce the concentration of residual ruthenium from the organic products of several alkene and ene-yne metathesis reactions, under a variety of different conditions.

UR - https://www.scopus.com/pages/publications/84887034356

U2 - 10.1021/ol402339e

DO - 10.1021/ol402339e

M3 - Article

AN - SCOPUS:84887034356

SN - 1523-7060

VL - 15

SP - 5416

EP - 5419

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Removal of ruthenium using a silica gel supported reagent

Abstract

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