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Relativistic effects on magnetic resonance parameters and other properties of inorganic molecules and metal complexes

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

30 Scopus citations

Abstract

This chapter is concerned with relativistic effects on molecular properties other than energy and structure. The chapter has two parts: The first part consists of a brief overview of theoretical formalisms to calculate energy-derivative properties. In the second part benchmark data and selected case studies are presented. The examples emphasize inorganic and organometallic systems but data for some popular benchmark series of molecules with main group atoms are also included. Molecular properties that are discussed in detail this chapter include NMR and EPR parameters, electric field gradients, electronic spectra, and polarizabilities.

Original languageEnglish
Title of host publicationChallenges and Advances in Computational Chemistry and Physics
PublisherSpringer
Pages521-598
Number of pages78
DOIs
StatePublished - 2010

Publication series

NameChallenges and Advances in Computational Chemistry and Physics
Volume10
ISSN (Print)2542-4491
ISSN (Electronic)2542-4483

Keywords

  • Absorption spectra
  • Chemical shift
  • Dipole moment
  • Electric field gradient
  • Electron paramagnetic resonance
  • g-tensor
  • Hyperfine tensor
  • Molecular response properties
  • Nuclear magnetic resonance
  • Nuclear quadrupole coupling
  • Polarizability
  • Relativistic effects
  • Spin–orbit coupling

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