Reduction of the 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl carbocation by sodium sulfite

John P. Richard

doi:10.1016/S0040-4039(01)80312-9

Reduction of the 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl carbocation by sodium sulfite

John P. Richard

Chemistry

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Abstract

The rate of the reaction of sodium sulfite with 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl bromide in 20% acetonitrile in water is kinetically zero-order in sulfite anion and at 0.27 M SO₃^2- the reaction gives a 0.67:0.15:0.18 ratio of the C-1 sulfite adduct, the water adduct and the novel reduction product 1-(4-thiomethylphenyl)-2,2,2-trifluoroethane, respectively.

Original language	English
Pages (from-to)	23-26
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	1
DOIs	https://doi.org/10.1016/S0040-4039(01)80312-9
State	Published - 1989

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title = "Reduction of the 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl carbocation by sodium sulfite",

abstract = "The rate of the reaction of sodium sulfite with 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl bromide in 20\% acetonitrile in water is kinetically zero-order in sulfite anion and at 0.27 M SO32- the reaction gives a 0.67:0.15:0.18 ratio of the C-1 sulfite adduct, the water adduct and the novel reduction product 1-(4-thiomethylphenyl)-2,2,2-trifluoroethane, respectively.",

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journal = "Tetrahedron Letters",

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T1 - Reduction of the 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl carbocation by sodium sulfite

AU - Richard, John P.

PY - 1989

Y1 - 1989

N2 - The rate of the reaction of sodium sulfite with 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl bromide in 20% acetonitrile in water is kinetically zero-order in sulfite anion and at 0.27 M SO32- the reaction gives a 0.67:0.15:0.18 ratio of the C-1 sulfite adduct, the water adduct and the novel reduction product 1-(4-thiomethylphenyl)-2,2,2-trifluoroethane, respectively.

AB - The rate of the reaction of sodium sulfite with 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl bromide in 20% acetonitrile in water is kinetically zero-order in sulfite anion and at 0.27 M SO32- the reaction gives a 0.67:0.15:0.18 ratio of the C-1 sulfite adduct, the water adduct and the novel reduction product 1-(4-thiomethylphenyl)-2,2,2-trifluoroethane, respectively.

UR - https://www.scopus.com/pages/publications/45249125313

U2 - 10.1016/S0040-4039(01)80312-9

DO - 10.1016/S0040-4039(01)80312-9

M3 - Article

AN - SCOPUS:45249125313

SN - 0040-4039

VL - 30

SP - 23

EP - 26

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 1

ER -

Reduction of the 1-(4-thiomethylphenyl)-2,2,2-trifluoroethyl carbocation by sodium sulfite

Abstract

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