Rearrangement of o-protonated metal carbonyl clusters. Conversion of HRu3(COH)(CO)10 to H2Ru3(CO)11

J. B. Keister

doi:10.1016/S0022-328X(00)85919-7

Rearrangement of o-protonated metal carbonyl clusters. Conversion of HRu₃(COH)(CO)₁₀ to H₂Ru₃(CO)₁₁

J. B. Keister

Chemistry

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Abstract

Protonation of the HRu₃(CO)₁₁ anion at-60°C gives HRu₃(COH)(CO)₁₀ as the initial product, but at higher temperatures rearrangement to H₂Ru₃(CO)₁₁ is observed. The latter product is proposed to contain one bridging and one terminal hydridge ligand. At 25°C H₂Ru₃(CO)₁₁ decomposes rapidly to Ru₃(Co)₁₂.

Original language	English
Pages (from-to)	C36-C38
Journal	Journal of Organometallic Chemistry
Volume	190
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)85919-7
State	Published - May 6 1980

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title = "Rearrangement of o-protonated metal carbonyl clusters. Conversion of HRu3(COH)(CO)10 to H2Ru3(CO)11",

abstract = "Protonation of the HRu3(CO)11 anion at-60°C gives HRu3(COH)(CO)10 as the initial product, but at higher temperatures rearrangement to H2Ru3(CO)11 is observed. The latter product is proposed to contain one bridging and one terminal hydridge ligand. At 25°C H2Ru3(CO)11 decomposes rapidly to Ru3(Co)12.",

author = "Keister, \{J. B.\}",

year = "1980",

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doi = "10.1016/S0022-328X(00)85919-7",

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T1 - Rearrangement of o-protonated metal carbonyl clusters. Conversion of HRu3(COH)(CO)10 to H2Ru3(CO)11

AU - Keister, J. B.

PY - 1980/5/6

Y1 - 1980/5/6

N2 - Protonation of the HRu3(CO)11 anion at-60°C gives HRu3(COH)(CO)10 as the initial product, but at higher temperatures rearrangement to H2Ru3(CO)11 is observed. The latter product is proposed to contain one bridging and one terminal hydridge ligand. At 25°C H2Ru3(CO)11 decomposes rapidly to Ru3(Co)12.

AB - Protonation of the HRu3(CO)11 anion at-60°C gives HRu3(COH)(CO)10 as the initial product, but at higher temperatures rearrangement to H2Ru3(CO)11 is observed. The latter product is proposed to contain one bridging and one terminal hydridge ligand. At 25°C H2Ru3(CO)11 decomposes rapidly to Ru3(Co)12.

UR - https://www.scopus.com/pages/publications/0039151356

U2 - 10.1016/S0022-328X(00)85919-7

DO - 10.1016/S0022-328X(00)85919-7

M3 - Article

AN - SCOPUS:0039151356

SN - 0022-328X

VL - 190

SP - C36-C38

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Rearrangement of o-protonated metal carbonyl clusters. Conversion of HRu₃(COH)(CO)₁₀ to H₂Ru₃(CO)₁₁

Abstract

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