Reaction of ethylene with the unsaturated cluster complex H2Os3 (CO)10

Jerome B. Keister; John R. Shapley

doi:10.1016/S0022-328X(00)80710-X

Reaction of ethylene with the unsaturated cluster complex H₂Os₃ (CO)₁₀

Jerome B. Keister
, John R. Shapley

Chemistry

University of Illinois at Urbana-Champaign

Research output: Contribution to journal › Article › peer-review

131 Scopus citations

Abstract

Treatment of H₂Os₃(CO)₁₀ with excess ethylene forms ethane and a hydridovinyl cluster complex HOs₃(CO)₁₀(CHCH₂), which rearranges in refluxing octane to the vinylidene complex H₂Os₃(CO)₉(CCH₂).

Original language	English
Pages (from-to)	C29-C31
Journal	Journal of Organometallic Chemistry
Volume	85
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)80710-X
State	Published - Feb 4 1975

Access to Document

10.1016/S0022-328X(00)80710-X

Cite this

@article{dc12d4b9140744069f692fd7d75e906a,

title = "Reaction of ethylene with the unsaturated cluster complex H2Os3 (CO)10",

abstract = "Treatment of H2Os3(CO)10 with excess ethylene forms ethane and a hydridovinyl cluster complex HOs3(CO)10(CHCH2), which rearranges in refluxing octane to the vinylidene complex H2Os3(CO)9(CCH2).",

author = "Keister, \{Jerome B.\} and Shapley, \{John R.\}",

year = "1975",

month = feb,

day = "4",

doi = "10.1016/S0022-328X(00)80710-X",

language = "English",

volume = "85",

pages = "C29--C31",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Reaction of ethylene with the unsaturated cluster complex H2Os3 (CO)10

AU - Keister, Jerome B.

AU - Shapley, John R.

PY - 1975/2/4

Y1 - 1975/2/4

N2 - Treatment of H2Os3(CO)10 with excess ethylene forms ethane and a hydridovinyl cluster complex HOs3(CO)10(CHCH2), which rearranges in refluxing octane to the vinylidene complex H2Os3(CO)9(CCH2).

AB - Treatment of H2Os3(CO)10 with excess ethylene forms ethane and a hydridovinyl cluster complex HOs3(CO)10(CHCH2), which rearranges in refluxing octane to the vinylidene complex H2Os3(CO)9(CCH2).

UR - https://www.scopus.com/pages/publications/0001998875

U2 - 10.1016/S0022-328X(00)80710-X

DO - 10.1016/S0022-328X(00)80710-X

M3 - Article

AN - SCOPUS:0001998875

SN - 0022-328X

VL - 85

SP - C29-C31

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Reaction of ethylene with the unsaturated cluster complex H₂Os₃ (CO)₁₀

Abstract

Access to Document

Other files and links

Fingerprint

Cite this