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Rational approximations of the integral of the Arrhenius function

  • Brookhaven National Laboratory

Research output: Contribution to journalArticlepeer-review

792 Scopus citations

Abstract

Rational approximations have been derived for the integral of the Arrhenius function {Mathematical expression}dT which is important in the kinetic analysis of thermogravimetric data. The first degree rational approximation is found to be equivalent to the Gorbachev approximation, i.e., RT2exp (-E/RT)/(E+2RT). The second degree rational approximation is more accurate than the Zsakó empirical approximation when E/RT < 1 and E/RT > 5. The third and higher degree rational approximations are found to be more accurate than any other previous approximation.

Original languageEnglish
Pages (from-to)445-447
Number of pages3
JournalJournal of Thermal Analysis
Volume11
Issue number3
DOIs
StatePublished - Jun 1977

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