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Rapid solubility determination using vapor-phase osmometry

  • SUNY Buffalo

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Because of the need for resource-sparing assays of the solubility of new drug candidates, we sought to develop and validate a rapid method for determining the solubility of nonvolatile pharmaceutical solids in water. Vapor-phase osmometry was used to determine the concentration of drugs in saturated solutions prepared by a rapid ultrasound-mediated dissolution protocol. The osmolality of saturated solutions as measured by the vapor- phase osmometer is an excellent predictor of the solubility of pharmaceutical solids in water. Each osmolality measurement requires less than 10 μl of saturated solution and takes less than 2 min to complete. For small-molecule drugs with solubilities greater than 10 g/kg, osmometry may prove to be a rapid and accurate method for determining the water solubilities of drugs.

Original languageEnglish
Pages (from-to)315-318
Number of pages4
JournalJournal of Biomolecular Screening
Volume4
Issue number6
DOIs
StatePublished - 1999

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