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Quenchometric strategies for determining O2 in the 99-100% region

  • SUNY Buffalo
  • not available
  • InnoSense LLC
  • Innosense Llc

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

We describe a luminescence-based quenchometric sensor arrays that exploit tailored class II xerogels doped with a luminophore (tris(4,7-diphenyl-1,10- phenanthroline)ruthenium(II) (Ru(dpp)3)2+), Pt(II) meso-tetra(N-methyl-4- pyridyl)porphyrin tetrachloride (PtTMP), or Pt(II) octaethylporphine (PtOEP)) in concert with an artificial neural network. The xerogel response to O2 is tuned by choice of luminophore dnd the xerogel composition. The xerogel composition is controlled by changing the sol precursors and their mole fractions. A three layer multilayer perceptron network with backward error propagation was used for training. The collective microarray platform exhibited the ability to discriminate O2 concentrations from 0.05% to 100% O2; in the 99-100% region the resolution is 0.2% O2.

Original languageEnglish
Title of host publication42nd International Conference on Environmental Systems 2012, ICES 2012
PublisherAIAA International
ISBN (Print)9781600869341
StatePublished - 2012
Event42nd International Conference on Environmental Systems 2012, ICES 2012 - , United States
Duration: Jul 15 2012Jul 19 2012

Publication series

Name42nd International Conference on Environmental Systems 2012, ICES 2012

Conference

Conference42nd International Conference on Environmental Systems 2012, ICES 2012
Country/TerritoryUnited States
Period07/15/1207/19/12

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