Protonation of (μ-H)3Ru3(μ3-CR)(CO)9. Evidence for the formation of an agostic metalhydrogencarbon bond

David K. Bower; Jerome B. Keister

doi:10.1016/0022-328X(86)80307-2

Protonation of (μ-H)₃Ru₃(μ₃-CR)(CO)₉. Evidence for the formation of an agostic metalhydrogencarbon bond

David K. Bower
, Jerome B. Keister

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Protonation of (μ-H)₃M₃(μ₃-CR)(CO)₉ (M = Ru, R = Et or M = Os, R = Me) by dissolution in HSO₃CF₃ yields H₃M₃(HCR)(CO)₉⁺, containing a MHC bridge. The products were characterized by ¹H and ¹³C NMR spectroscopy. Decompositions of other protonated methylidyne clusters from CH₃R and a variety of metal-containing products.

Original language	English
Pages (from-to)	c33-c36
Journal	Journal of Organometallic Chemistry
Volume	312
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(86)80307-2
State	Published - Sep 23 1986

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title = "Protonation of (μ-H)3Ru3(μ3-CR)(CO)9. Evidence for the formation of an agostic metalhydrogencarbon bond",

abstract = "Protonation of (μ-H)3M3(μ3-CR)(CO)9 (M = Ru, R = Et or M = Os, R = Me) by dissolution in HSO3CF3 yields H3M3(HCR)(CO)9+, containing a MHC bridge. The products were characterized by 1H and 13C NMR spectroscopy. Decompositions of other protonated methylidyne clusters from CH3R and a variety of metal-containing products.",

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T1 - Protonation of (μ-H)3Ru3(μ3-CR)(CO)9. Evidence for the formation of an agostic metalhydrogencarbon bond

AU - Bower, David K.

AU - Keister, Jerome B.

PY - 1986/9/23

Y1 - 1986/9/23

N2 - Protonation of (μ-H)3M3(μ3-CR)(CO)9 (M = Ru, R = Et or M = Os, R = Me) by dissolution in HSO3CF3 yields H3M3(HCR)(CO)9+, containing a MHC bridge. The products were characterized by 1H and 13C NMR spectroscopy. Decompositions of other protonated methylidyne clusters from CH3R and a variety of metal-containing products.

AB - Protonation of (μ-H)3M3(μ3-CR)(CO)9 (M = Ru, R = Et or M = Os, R = Me) by dissolution in HSO3CF3 yields H3M3(HCR)(CO)9+, containing a MHC bridge. The products were characterized by 1H and 13C NMR spectroscopy. Decompositions of other protonated methylidyne clusters from CH3R and a variety of metal-containing products.

UR - https://www.scopus.com/pages/publications/14544296644

U2 - 10.1016/0022-328X(86)80307-2

DO - 10.1016/0022-328X(86)80307-2

M3 - Article

AN - SCOPUS:14544296644

SN - 0022-328X

VL - 312

SP - c33-c36

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Protonation of (μ-H)₃Ru₃(μ₃-CR)(CO)₉. Evidence for the formation of an agostic metalhydrogencarbon bond

Abstract

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