Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L3 -edge Puzzle

Dumitru Claudiu Sergentu; Corwin H. Booth; Jochen Autschbach

doi:10.1002/chem.202101162

Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L₃ -edge Puzzle

Dumitru Claudiu Sergentu
, Corwin H. Booth
, Jochen Autschbach

Chemistry

SUNY Buffalo
Lawrence Berkeley National Laboratory

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Invited for the cover of this issue are Prof. Jochen Autschbach and Dr. Dumitru-Claudiu Sergentu of State University of New York at Buffalo, and Dr. Corwin H. Booth of Lawrence Berkeley National Laboratory. The image depicts high-energy X-ray beams as lightnings probing Ce at the L3 edge in the iconic covalent-bonded Ce(C8 H8 )2 and in CeO2 . The mountain peaks in the background represent the double-peaked L3 edges. The peaks turn out to be intuitively interpreted in terms of localized orbitals and hence metal oxidation states. Read the full text of the article at 10.1002/chem.202100145.

Original language	English
Pages (from-to)	7188
Number of pages	1
Journal	Chemistry - A European Journal
Volume	27
Issue number	25
DOIs	https://doi.org/10.1002/chem.202101162
State	Published - May 3 2021

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title = "Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L3 -edge Puzzle",

abstract = "Invited for the cover of this issue are Prof. Jochen Autschbach and Dr. Dumitru-Claudiu Sergentu of State University of New York at Buffalo, and Dr. Corwin H. Booth of Lawrence Berkeley National Laboratory. The image depicts high-energy X-ray beams as lightnings probing Ce at the L3 edge in the iconic covalent-bonded Ce(C8 H8 )2 and in CeO2 . The mountain peaks in the background represent the double-peaked L3 edges. The peaks turn out to be intuitively interpreted in terms of localized orbitals and hence metal oxidation states. Read the full text of the article at 10.1002/chem.202100145.",

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AU - Booth, Corwin H.

AU - Autschbach, Jochen

PY - 2021/5/3

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N2 - Invited for the cover of this issue are Prof. Jochen Autschbach and Dr. Dumitru-Claudiu Sergentu of State University of New York at Buffalo, and Dr. Corwin H. Booth of Lawrence Berkeley National Laboratory. The image depicts high-energy X-ray beams as lightnings probing Ce at the L3 edge in the iconic covalent-bonded Ce(C8 H8 )2 and in CeO2 . The mountain peaks in the background represent the double-peaked L3 edges. The peaks turn out to be intuitively interpreted in terms of localized orbitals and hence metal oxidation states. Read the full text of the article at 10.1002/chem.202100145.

AB - Invited for the cover of this issue are Prof. Jochen Autschbach and Dr. Dumitru-Claudiu Sergentu of State University of New York at Buffalo, and Dr. Corwin H. Booth of Lawrence Berkeley National Laboratory. The image depicts high-energy X-ray beams as lightnings probing Ce at the L3 edge in the iconic covalent-bonded Ce(C8 H8 )2 and in CeO2 . The mountain peaks in the background represent the double-peaked L3 edges. The peaks turn out to be intuitively interpreted in terms of localized orbitals and hence metal oxidation states. Read the full text of the article at 10.1002/chem.202100145.

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Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L₃ -edge Puzzle

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