Potential—Time Curves of Thallium, Lead, Cadmium, and Bismuth at Thin Mercury Film Electrodes

Frederick L. Marsh; Stanley Bruckenstein

doi:10.1021/ac60243a011

Potential—Time Curves of Thallium, Lead, Cadmium, and Bismuth at Thin Mercury Film Electrodes

Frederick L. Marsh
, Stanley Bruckenstein

Chemistry

University of Minnesota Twin Cities

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Concentrated metal amalgams may be deposited as a 4000-A. layer upon a rotating platinum electrode by simultaneously depositing mercury and metal from a nitric acid solution of mercurous (or mercuric) and metal ion. The potential-time curve obtained by chemical stripping with mercurous (or mercuric) nitrate can be predicted within experimental error. A potential-time expression is given, allowing for the changes in activity coefficients of mercury and the metal in amalgams, the latter being the most important correction.

Original language	English
Pages (from-to)	1498-1502
Number of pages	5
Journal	Analytical Chemistry
Volume	38
Issue number	11
DOIs	https://doi.org/10.1021/ac60243a011
State	Published - 1966

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title = "Potential—Time Curves of Thallium, Lead, Cadmium, and Bismuth at Thin Mercury Film Electrodes",

abstract = "Concentrated metal amalgams may be deposited as a 4000-A. layer upon a rotating platinum electrode by simultaneously depositing mercury and metal from a nitric acid solution of mercurous (or mercuric) and metal ion. The potential-time curve obtained by chemical stripping with mercurous (or mercuric) nitrate can be predicted within experimental error. A potential-time expression is given, allowing for the changes in activity coefficients of mercury and the metal in amalgams, the latter being the most important correction.",

author = "Marsh, \{Frederick L.\} and Stanley Bruckenstein",

year = "1966",

doi = "10.1021/ac60243a011",

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journal = "Analytical Chemistry",

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publisher = "American Chemical Society",

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T1 - Potential—Time Curves of Thallium, Lead, Cadmium, and Bismuth at Thin Mercury Film Electrodes

AU - Marsh, Frederick L.

AU - Bruckenstein, Stanley

PY - 1966

Y1 - 1966

N2 - Concentrated metal amalgams may be deposited as a 4000-A. layer upon a rotating platinum electrode by simultaneously depositing mercury and metal from a nitric acid solution of mercurous (or mercuric) and metal ion. The potential-time curve obtained by chemical stripping with mercurous (or mercuric) nitrate can be predicted within experimental error. A potential-time expression is given, allowing for the changes in activity coefficients of mercury and the metal in amalgams, the latter being the most important correction.

AB - Concentrated metal amalgams may be deposited as a 4000-A. layer upon a rotating platinum electrode by simultaneously depositing mercury and metal from a nitric acid solution of mercurous (or mercuric) and metal ion. The potential-time curve obtained by chemical stripping with mercurous (or mercuric) nitrate can be predicted within experimental error. A potential-time expression is given, allowing for the changes in activity coefficients of mercury and the metal in amalgams, the latter being the most important correction.

UR - https://www.scopus.com/pages/publications/33947335148

U2 - 10.1021/ac60243a011

DO - 10.1021/ac60243a011

M3 - Article

AN - SCOPUS:33947335148

SN - 0003-2700

VL - 38

SP - 1498

EP - 1502

JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 11

ER -

Potential—Time Curves of Thallium, Lead, Cadmium, and Bismuth at Thin Mercury Film Electrodes

Abstract

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