Photocatalysis of hydrogenation and isomerization of alkenes by cis-HMn(CO)4PPh3

Paula L. Bogdan; Patrick J. Sullivan; Thomas A. Donovan; Jim D. Atwood

doi:10.1016/0022-328X(84)80323-X

Photocatalysis of hydrogenation and isomerization of alkenes by cis-HMn(CO)₄PPh₃

Paula L. Bogdan
, Patrick J. Sullivan
, Thomas A. Donovan
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Photolysis of cis-HMn(CO)₄PPh₃ in the presence of H₂ and 1-alkene results in catalytic hydrogenation and isomerization of the alkene. The isomerization leads to cis- and trans-2-alkene in the presence or absence of H₂. Catalytic hydrogenation also occurs when cis-CH₃Mn(CO)₄PPh₃ is irradiated in the presence of H₂; use of D₂ leads exclusively to CH₃D. The possible mechanism of the hydrogenation is discussed.

Original language	English
Pages (from-to)	c51-c54
Journal	Journal of Organometallic Chemistry
Volume	269
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(84)80323-X
State	Published - Jul 17 1984

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title = "Photocatalysis of hydrogenation and isomerization of alkenes by cis-HMn(CO)4PPh3",

abstract = "Photolysis of cis-HMn(CO)4PPh3 in the presence of H2 and 1-alkene results in catalytic hydrogenation and isomerization of the alkene. The isomerization leads to cis- and trans-2-alkene in the presence or absence of H2. Catalytic hydrogenation also occurs when cis-CH3Mn(CO)4PPh3 is irradiated in the presence of H2; use of D2 leads exclusively to CH3D. The possible mechanism of the hydrogenation is discussed.",

author = "Bogdan, \{Paula L.\} and Sullivan, \{Patrick J.\} and Donovan, \{Thomas A.\} and Atwood, \{Jim D.\}",

year = "1984",

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doi = "10.1016/0022-328X(84)80323-X",

language = "English",

volume = "269",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Photocatalysis of hydrogenation and isomerization of alkenes by cis-HMn(CO)4PPh3

AU - Bogdan, Paula L.

AU - Sullivan, Patrick J.

AU - Donovan, Thomas A.

AU - Atwood, Jim D.

PY - 1984/7/17

Y1 - 1984/7/17

N2 - Photolysis of cis-HMn(CO)4PPh3 in the presence of H2 and 1-alkene results in catalytic hydrogenation and isomerization of the alkene. The isomerization leads to cis- and trans-2-alkene in the presence or absence of H2. Catalytic hydrogenation also occurs when cis-CH3Mn(CO)4PPh3 is irradiated in the presence of H2; use of D2 leads exclusively to CH3D. The possible mechanism of the hydrogenation is discussed.

AB - Photolysis of cis-HMn(CO)4PPh3 in the presence of H2 and 1-alkene results in catalytic hydrogenation and isomerization of the alkene. The isomerization leads to cis- and trans-2-alkene in the presence or absence of H2. Catalytic hydrogenation also occurs when cis-CH3Mn(CO)4PPh3 is irradiated in the presence of H2; use of D2 leads exclusively to CH3D. The possible mechanism of the hydrogenation is discussed.

UR - https://www.scopus.com/pages/publications/14244268109

U2 - 10.1016/0022-328X(84)80323-X

DO - 10.1016/0022-328X(84)80323-X

M3 - Article

AN - SCOPUS:14244268109

SN - 0022-328X

VL - 269

SP - c51-c54

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Photocatalysis of hydrogenation and isomerization of alkenes by cis-HMn(CO)₄PPh₃

Abstract

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