Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts

Karthika J. Kadassery; David C. Lacy

doi:10.1039/C9DT00529C

Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts

Karthika J. Kadassery
, David C. Lacy

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Mn(i) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO) ₅ as a synthon in place of typical Mn(CO) ₅ Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and even C-H bonds.

Original language	English
Pages (from-to)	4467-4470
Number of pages	4
Journal	Dalton Transactions
Volume	48
Issue number	14
DOIs	https://doi.org/10.1039/C9DT00529C
State	Published - 2019

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title = "Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts",

abstract = " Mn(i) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO) 5 as a synthon in place of typical Mn(CO) 5 Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and even C-H bonds.",

author = "Kadassery, \{Karthika J.\} and Lacy, \{David C.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/C9DT00529C",

language = "English",

volume = "48",

pages = "4467--4470",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts

AU - Kadassery, Karthika J.

AU - Lacy, David C.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Mn(i) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO) 5 as a synthon in place of typical Mn(CO) 5 Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and even C-H bonds.

AB - Mn(i) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO) 5 as a synthon in place of typical Mn(CO) 5 Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and even C-H bonds.

UR - https://www.scopus.com/pages/publications/85063736479

U2 - 10.1039/C9DT00529C

DO - 10.1039/C9DT00529C

M3 - Article

C2 - 30860251

AN - SCOPUS:85063736479

SN - 1477-9226

VL - 48

SP - 4467

EP - 4470

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts

Abstract

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