Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H3Ru3(CX)(CO)9-nlN+ (X = OMe, L = PPh3, n = 2, 3; X = OMe, L = AsPh3, n = 3; X = SEt, NMeCh2Ph, L = Pph3, n = 3) and the Decomposition Products [H3Ru3(CO)7L3]+

William G. Feighery; Robert D. Allendoerfer; Jerome B. Keister

doi:10.1021/om00159a006

Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H₃Ru₃(CX)(CO)_9-nl_N⁺ (X = OMe, L = PPh₃, n = 2, 3; X = OMe, L = AsPh₃, n = 3; X = SEt, NMeCh₂Ph, L = Pph₃, n = 3) and the Decomposition Products [H₃Ru₃(CO)₇L₃]⁺

William G. Feighery
, Robert D. Allendoerfer
, Jerome B. Keister

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Chemical or electrochemical oxidation of [H₃Ru₃(CX)(CO)_9-nL_n] (X = OMe, L = PPh₃, n = 2, 3; X = OMe, L = AsPh₃, n = 3; X = SEt, NMeBz, L = PPh₃, n = 3) reversibly forms the corresponding cation radical [H₃Ru₃(CX)(CO)_9-nL_n]⁺. Decomposition of [H₃Ru₃-(COMe)(CO)₆L₃]⁺ generates [H₃Ru₃(CO)₇L₃]⁺. The complexes [H₃Ru₃(CX)(CO)_9-n L_n]⁺ were characterized by¹H NMR and ERR spectroscopies. The complexes [H₃Ru₃- (CO)₇L₃]⁺ were characterized by¹H and³¹P NMR spectroscopies and by comparison of the spectra with those of [H₃Os₃(CO)_10-nL_n]+ (L = PPh₃, n = 0, 1).

Original language	English
Pages (from-to)	2424-2426
Number of pages	3
Journal	Organometallics
Volume	9
Issue number	9
DOIs	https://doi.org/10.1021/om00159a006
State	Published - 1990

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Feighery, W. G., Allendoerfer, R. D., & Keister, J. B. (1990). Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H₃Ru₃(CX)(CO)_9-nl_N⁺ (X = OMe, L = PPh₃, n = 2, 3; X = OMe, L = AsPh₃, n = 3; X = SEt, NMeCh₂Ph, L = Pph₃, n = 3) and the Decomposition Products [H₃Ru₃(CO)₇L₃]⁺. Organometallics, 9(9), 2424-2426. https://doi.org/10.1021/om00159a006

Feighery, William G. ; Allendoerfer, Robert D. ; Keister, Jerome B. / Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H₃Ru₃(CX)(CO)_9-nl_N⁺ (X = OMe, L = PPh₃, n = 2, 3; X = OMe, L = AsPh₃, n = 3; X = SEt, NMeCh₂Ph, L = Pph₃, n = 3) and the Decomposition Products [H₃Ru₃(CO)₇L₃]⁺. In: Organometallics. 1990 ; Vol. 9, No. 9. pp. 2424-2426.

@article{743593b1980947e0b3912e64ab12711c,

title = "Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H3Ru3(CX)(CO)9-nlN+ (X = OMe, L = PPh3, n = 2, 3; X = OMe, L = AsPh3, n = 3; X = SEt, NMeCh2Ph, L = Pph3, n = 3) and the Decomposition Products [H3Ru3(CO)7L3]+",

abstract = "Chemical or electrochemical oxidation of [H3Ru3(CX)(CO)9-nLn] (X = OMe, L = PPh3, n = 2, 3; X = OMe, L = AsPh3, n = 3; X = SEt, NMeBz, L = PPh3, n = 3) reversibly forms the corresponding cation radical [H3Ru3(CX)(CO)9-nLn]+. Decomposition of [H3Ru3-(COMe)(CO)6L3]+ generates [H3Ru3(CO)7L3]+. The complexes [H3Ru3(CX)(CO)9-n Ln]+ were characterized by1H NMR and ERR spectroscopies. The complexes [H3Ru3- (CO)7L3]+ were characterized by1H and31P NMR spectroscopies and by comparison of the spectra with those of [H3Os3(CO)10-nLn]+ (L = PPh3, n = 0, 1).",

author = "Feighery, \{William G.\} and Allendoerfer, \{Robert D.\} and Keister, \{Jerome B.\}",

year = "1990",

doi = "10.1021/om00159a006",

language = "English",

volume = "9",

pages = "2424--2426",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

Feighery, WG, Allendoerfer, RD & Keister, JB 1990, 'Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H₃Ru₃(CX)(CO)_9-nl_N⁺ (X = OMe, L = PPh₃, n = 2, 3; X = OMe, L = AsPh₃, n = 3; X = SEt, NMeCh₂Ph, L = Pph₃, n = 3) and the Decomposition Products [H₃Ru₃(CO)₇L₃]⁺', Organometallics, vol. 9, no. 9, pp. 2424-2426. https://doi.org/10.1021/om00159a006

Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H₃Ru₃(CX)(CO)_9-nl_N⁺ (X = OMe, L = PPh₃, n = 2, 3; X = OMe, L = AsPh₃, n = 3; X = SEt, NMeCh₂Ph, L = Pph₃, n = 3) and the Decomposition Products [H₃Ru₃(CO)₇L₃]⁺. / Feighery, William G.; Allendoerfer, Robert D.; Keister, Jerome B.
In: Organometallics, Vol. 9, No. 9, 1990, p. 2424-2426.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Oxidation of (Alkylidyne)triruthenium Clusters. Spectroscopic Characterization of the Cation Radicals [H3Ru3(CX)(CO)9-nlN+ (X = OMe, L = PPh3, n = 2, 3; X = OMe, L = AsPh3, n = 3; X = SEt, NMeCh2Ph, L = Pph3, n = 3) and the Decomposition Products [H3Ru3(CO)7L3]+

AU - Feighery, William G.

AU - Allendoerfer, Robert D.

AU - Keister, Jerome B.

PY - 1990

Y1 - 1990

N2 - Chemical or electrochemical oxidation of [H3Ru3(CX)(CO)9-nLn] (X = OMe, L = PPh3, n = 2, 3; X = OMe, L = AsPh3, n = 3; X = SEt, NMeBz, L = PPh3, n = 3) reversibly forms the corresponding cation radical [H3Ru3(CX)(CO)9-nLn]+. Decomposition of [H3Ru3-(COMe)(CO)6L3]+ generates [H3Ru3(CO)7L3]+. The complexes [H3Ru3(CX)(CO)9-n Ln]+ were characterized by1H NMR and ERR spectroscopies. The complexes [H3Ru3- (CO)7L3]+ were characterized by1H and31P NMR spectroscopies and by comparison of the spectra with those of [H3Os3(CO)10-nLn]+ (L = PPh3, n = 0, 1).

AB - Chemical or electrochemical oxidation of [H3Ru3(CX)(CO)9-nLn] (X = OMe, L = PPh3, n = 2, 3; X = OMe, L = AsPh3, n = 3; X = SEt, NMeBz, L = PPh3, n = 3) reversibly forms the corresponding cation radical [H3Ru3(CX)(CO)9-nLn]+. Decomposition of [H3Ru3-(COMe)(CO)6L3]+ generates [H3Ru3(CO)7L3]+. The complexes [H3Ru3(CX)(CO)9-n Ln]+ were characterized by1H NMR and ERR spectroscopies. The complexes [H3Ru3- (CO)7L3]+ were characterized by1H and31P NMR spectroscopies and by comparison of the spectra with those of [H3Os3(CO)10-nLn]+ (L = PPh3, n = 0, 1).

UR - https://www.scopus.com/pages/publications/0039005339

U2 - 10.1021/om00159a006

DO - 10.1021/om00159a006

M3 - Article

AN - SCOPUS:0039005339

SN - 0276-7333

VL - 9

SP - 2424

EP - 2426

JO - Organometallics

JF - Organometallics

IS - 9