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Orbitals: Some fiction and some facts

Research output: Contribution to journalArticlepeer-review

55 Scopus citations

Abstract

The use of electron orbitals in quantum theory and chemistry is discussed. Common misconceptions are highlighted. Suggestions are made how chemistry educators may describe orbitals in the first and second year college curriculum more accurately without introducing unwanted technicalities. A comparison is made of different ways of graphically representing orbitals. The connection of orbital delocalization and electron delocalization is explained by using graphical representations of canonical and localized molecular orbitals for water, benzene, and linear hexatriene.

Original languageEnglish
Pages (from-to)1032-1040
Number of pages9
JournalJournal of Chemical Education
Volume89
Issue number8
DOIs
StatePublished - Jul 10 2012

Keywords

  • First-Year Undergraduate/General
  • Interdisciplinary/Multidisciplinary
  • Misconceptions/Discrepant Events
  • MO Theory
  • Physical Chemistry
  • Quantum Chemistry
  • Second-Year Undergraduate
  • Upper-Division Undergraduate

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