Octahedral Ru[II] complexes containing the dipyridophenazine ring system. Novel fluorescent probes for nucleic acid structure

Gary D. Jaycox; Alan E. Friedman; Nicholas J. Turro; Jacqueline K. Barton

Octahedral Ru[II] complexes containing the dipyridophenazine ring system. Novel fluorescent probes for nucleic acid structure

Gary D. Jaycox
, Alan E. Friedman
, Nicholas J. Turro
, Jacqueline K. Barton

School of Engineering and Applied Sciences

Columbia University

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

Over the last decade, efforts in our laboratory have led to a novel class of DNA probes based on chiral, octahedral metal complexes. The unique DNA binding affinity of tris(1,10-phenanthroline) Ru[II] is now well documented. For this and related derivatives, DNA binding is generally accompanied by strong luminescence enhancements and absorption hypochromism in the intense MLCT band associated with the probe. Herein, we describe the photophysical properties of a new series of Ru[II] probes that contain the dipyridophenazine (DPPZ) ring system.

Original language	English
Pages (from-to)	634-635
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	32
Issue number	1
State	Published - Apr 1991
Event	Papers presented at the Atlanta Meeting 1991 of the ACS, Division of Polymer Chemistry - Atlanta, GA, USA Duration: Apr 14 1991 → Apr 19 1991

Cite this

@article{e062f73be4ef44488a41a999381e4a92,

title = "Octahedral Ru[II] complexes containing the dipyridophenazine ring system. Novel fluorescent probes for nucleic acid structure",

abstract = "Over the last decade, efforts in our laboratory have led to a novel class of DNA probes based on chiral, octahedral metal complexes. The unique DNA binding affinity of tris(1,10-phenanthroline) Ru[II] is now well documented. For this and related derivatives, DNA binding is generally accompanied by strong luminescence enhancements and absorption hypochromism in the intense MLCT band associated with the probe. Herein, we describe the photophysical properties of a new series of Ru[II] probes that contain the dipyridophenazine (DPPZ) ring system.",

author = "Jaycox, \{Gary D.\} and Friedman, \{Alan E.\} and Turro, \{Nicholas J.\} and Barton, \{Jacqueline K.\}",

year = "1991",

month = apr,

language = "English",

volume = "32",

pages = "634--635",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "1",

note = "Papers presented at the Atlanta Meeting 1991 of the ACS, Division of Polymer Chemistry ; Conference date: 14-04-1991 Through 19-04-1991",

}

Octahedral Ru[II] complexes containing the dipyridophenazine ring system. Novel fluorescent probes for nucleic acid structure. / Jaycox, Gary D.; Friedman, Alan E.; Turro, Nicholas J. et al.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 32, No. 1, 04.1991, p. 634-635.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Octahedral Ru[II] complexes containing the dipyridophenazine ring system. Novel fluorescent probes for nucleic acid structure

AU - Jaycox, Gary D.

AU - Friedman, Alan E.

AU - Turro, Nicholas J.

AU - Barton, Jacqueline K.

PY - 1991/4

Y1 - 1991/4

N2 - Over the last decade, efforts in our laboratory have led to a novel class of DNA probes based on chiral, octahedral metal complexes. The unique DNA binding affinity of tris(1,10-phenanthroline) Ru[II] is now well documented. For this and related derivatives, DNA binding is generally accompanied by strong luminescence enhancements and absorption hypochromism in the intense MLCT band associated with the probe. Herein, we describe the photophysical properties of a new series of Ru[II] probes that contain the dipyridophenazine (DPPZ) ring system.

AB - Over the last decade, efforts in our laboratory have led to a novel class of DNA probes based on chiral, octahedral metal complexes. The unique DNA binding affinity of tris(1,10-phenanthroline) Ru[II] is now well documented. For this and related derivatives, DNA binding is generally accompanied by strong luminescence enhancements and absorption hypochromism in the intense MLCT band associated with the probe. Herein, we describe the photophysical properties of a new series of Ru[II] probes that contain the dipyridophenazine (DPPZ) ring system.

UR - https://www.scopus.com/pages/publications/0026138481

M3 - Conference article

AN - SCOPUS:0026138481

SN - 0032-3934

VL - 32

SP - 634

EP - 635

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 1

T2 - Papers presented at the Atlanta Meeting 1991 of the ACS, Division of Polymer Chemistry

Y2 - 14 April 1991 through 19 April 1991

ER -

Octahedral Ru[II] complexes containing the dipyridophenazine ring system. Novel fluorescent probes for nucleic acid structure

Abstract

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