NiCl2 on γ-alumina as selective adsorbents for acetylene over ethylene

Adriaan J. Kodde; Joel Padin; Peter J. Van Der Meer; Marjo C. Mittelmeijer-Hazeleger; Alfred Bliek; Ralph T. Yang

doi:10.1021/ie000080f

NiCl₂ on γ-alumina as selective adsorbents for acetylene over ethylene

Adriaan J. Kodde
, Joel Padin
, Peter J. Van Der Meer
, Marjo C. Mittelmeijer-Hazeleger
, Alfred Bliek
, Ralph T. Yang

Department of Chemical and Biological Engineering

University of Amsterdam
University of Michigan, Ann Arbor

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

It has been found that previous results on selective adsorption of acetylene over ethylene and ethane reported by Yang et al. were influenced to a significant extent by acetone impurities (in acetylene). This work reports corrected adsorption isotherm results with acetone carefully removed on γ-alumina and monolayer NiCl₂/γ-alumina. For both sorbents, adsorption strengths followed the rank order acetylene > ethylene. The selectivity towards acetylene of NiCl₂/γ-alumina is higher compared to the bare γ-alumina.

Original language	English
Pages (from-to)	3108-3111
Number of pages	4
Journal	Industrial and Engineering Chemistry Research
Volume	39
Issue number	8
DOIs	https://doi.org/10.1021/ie000080f
State	Published - 2000

Access to Document

10.1021/ie000080f

Cite this

@article{c08cc3e370a24149b3e40fa6b0ad35c7,

title = "NiCl2 on γ-alumina as selective adsorbents for acetylene over ethylene",

abstract = "It has been found that previous results on selective adsorption of acetylene over ethylene and ethane reported by Yang et al. were influenced to a significant extent by acetone impurities (in acetylene). This work reports corrected adsorption isotherm results with acetone carefully removed on γ-alumina and monolayer NiCl2/γ-alumina. For both sorbents, adsorption strengths followed the rank order acetylene > ethylene. The selectivity towards acetylene of NiCl2/γ-alumina is higher compared to the bare γ-alumina.",

author = "Kodde, \{Adriaan J.\} and Joel Padin and \{Van Der Meer\}, \{Peter J.\} and Mittelmeijer-Hazeleger, \{Marjo C.\} and Alfred Bliek and Yang, \{Ralph T.\}",

year = "2000",

doi = "10.1021/ie000080f",

language = "English",

volume = "39",

pages = "3108--3111",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - NiCl2 on γ-alumina as selective adsorbents for acetylene over ethylene

AU - Kodde, Adriaan J.

AU - Padin, Joel

AU - Van Der Meer, Peter J.

AU - Mittelmeijer-Hazeleger, Marjo C.

AU - Bliek, Alfred

AU - Yang, Ralph T.

PY - 2000

Y1 - 2000

N2 - It has been found that previous results on selective adsorption of acetylene over ethylene and ethane reported by Yang et al. were influenced to a significant extent by acetone impurities (in acetylene). This work reports corrected adsorption isotherm results with acetone carefully removed on γ-alumina and monolayer NiCl2/γ-alumina. For both sorbents, adsorption strengths followed the rank order acetylene > ethylene. The selectivity towards acetylene of NiCl2/γ-alumina is higher compared to the bare γ-alumina.

AB - It has been found that previous results on selective adsorption of acetylene over ethylene and ethane reported by Yang et al. were influenced to a significant extent by acetone impurities (in acetylene). This work reports corrected adsorption isotherm results with acetone carefully removed on γ-alumina and monolayer NiCl2/γ-alumina. For both sorbents, adsorption strengths followed the rank order acetylene > ethylene. The selectivity towards acetylene of NiCl2/γ-alumina is higher compared to the bare γ-alumina.

UR - https://www.scopus.com/pages/publications/0034253718

U2 - 10.1021/ie000080f

DO - 10.1021/ie000080f

M3 - Article

AN - SCOPUS:0034253718

SN - 0888-5885

VL - 39

SP - 3108

EP - 3111

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 8

ER -

NiCl₂ on γ-alumina as selective adsorbents for acetylene over ethylene

Abstract

Access to Document

Other files and links

Fingerprint

Cite this