Nickel(II)-promoted rearrangements of Some N-substituted porphyrins

Kevin M. Smith; Ravindra K. Pandey; Kevin M. Snow

doi:10.1039/C39860001498

Nickel(II)-promoted rearrangements of Some N-substituted porphyrins

Kevin M. Smith
, Ravindra K. Pandey
, Kevin M. Snow

Institute for Lasers Photonics and Biophotonics

University of California at Davis

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Nickel(ll)-promoted rearrangement of an (N-methoxycarbonylmethy1)-substitutedp orphyrin (1) affords the nickel(ll) meso-methoxycarbonylmethylporphyrins, (3) and (4), produced by intramolecular migration of the N-substituent to carbon; when the pyrrole subunit containing the N-substituent also possesses a fi-methoxycarbonylmethyl group, 1e.g. compound (5)] a good yield of a nickel(rr) chlorin (7) is obtained.

Original language	English
Pages (from-to)	1498-1499
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
DOIs	https://doi.org/10.1039/C39860001498
State	Published - 1986

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title = "Nickel(II)-promoted rearrangements of Some N-substituted porphyrins",

abstract = "Nickel(ll)-promoted rearrangement of an (N-methoxycarbonylmethy1)-substitutedp orphyrin (1) affords the nickel(ll) meso-methoxycarbonylmethylporphyrins, (3) and (4), produced by intramolecular migration of the N-substituent to carbon; when the pyrrole subunit containing the N-substituent also possesses a fi-methoxycarbonylmethyl group, 1e.g. compound (5)] a good yield of a nickel(rr) chlorin (7) is obtained.",

author = "Smith, \{Kevin M.\} and Pandey, \{Ravindra K.\} and Snow, \{Kevin M.\}",

year = "1986",

doi = "10.1039/C39860001498",

language = "English",

pages = "1498--1499",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Nickel(II)-promoted rearrangements of Some N-substituted porphyrins

AU - Smith, Kevin M.

AU - Pandey, Ravindra K.

AU - Snow, Kevin M.

PY - 1986

Y1 - 1986

N2 - Nickel(ll)-promoted rearrangement of an (N-methoxycarbonylmethy1)-substitutedp orphyrin (1) affords the nickel(ll) meso-methoxycarbonylmethylporphyrins, (3) and (4), produced by intramolecular migration of the N-substituent to carbon; when the pyrrole subunit containing the N-substituent also possesses a fi-methoxycarbonylmethyl group, 1e.g. compound (5)] a good yield of a nickel(rr) chlorin (7) is obtained.

AB - Nickel(ll)-promoted rearrangement of an (N-methoxycarbonylmethy1)-substitutedp orphyrin (1) affords the nickel(ll) meso-methoxycarbonylmethylporphyrins, (3) and (4), produced by intramolecular migration of the N-substituent to carbon; when the pyrrole subunit containing the N-substituent also possesses a fi-methoxycarbonylmethyl group, 1e.g. compound (5)] a good yield of a nickel(rr) chlorin (7) is obtained.

UR - https://www.scopus.com/pages/publications/37049083843

U2 - 10.1039/C39860001498

DO - 10.1039/C39860001498

M3 - Article

AN - SCOPUS:37049083843

SN - 0022-4936

SP - 1498

EP - 1499

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

ER -

Nickel(II)-promoted rearrangements of Some N-substituted porphyrins

Abstract

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