Mono-sulfonated derivatives of triphenylphosphine (see abstract)

Mark R. Barton; Yuegang Zhang; Jim D. Atwood

doi:10.1080/0095897022000002295

Mono-sulfonated derivatives of triphenylphosphine (see abstract)

Mark R. Barton
, Yuegang Zhang
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Preparation of the ammonium salt of TPPMS, [NH₄]TPPMS, TPPMS = PPh₂(m-C₆H₄SO₃^-], greatly enhances water solubility and provides an efficient route to other metal complexes of TPPMS, M(TPPMS)₂ M = Mn²⁺, Co²⁺, Fe²⁺ and Ni²⁺. For Co²⁺ and Fe²⁺ the metal has an octahedral ligand environment with five water molecules and one TPPMS coordinated through the sulfonate oxygen; the second TPPMS is not coordinated. For Ni²⁺ the octahedral coordination sphere is composed of water molecules and the TPPMS ligands are not coordinated. Structures are fully reported for [NH4]TPPMS·1/2H₂O and [Fe(H₂O)₅(TPPMS)]TPPMS and partially reported for [Co(H₂O)₅TPPMS]TPPMS and [Ni(H₂O)₆]TPPMS₂·H₂O. All of the structures show hydrophobic regions consisting of aromatic rings and hydrophilic regions with hydrogen-bonding interactions.

Original language	English
Pages (from-to)	969-983
Number of pages	15
Journal	Journal of Coordination Chemistry
Volume	55
Issue number	8
DOIs	https://doi.org/10.1080/0095897022000002295
State	Published - 2002

Keywords

Coordination complexes
Hydrophilic interaction
TPPMS
Water-soluble phosphine ligands

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@article{9aada133bc874af9a7fb616e033a4764,

title = "Mono-sulfonated derivatives of triphenylphosphine (see abstract)",

abstract = "Preparation of the ammonium salt of TPPMS, [NH4]TPPMS, TPPMS = PPh2(m-C6H4SO3-], greatly enhances water solubility and provides an efficient route to other metal complexes of TPPMS, M(TPPMS)2 M = Mn2+, Co2+, Fe2+ and Ni2+. For Co2+ and Fe2+ the metal has an octahedral ligand environment with five water molecules and one TPPMS coordinated through the sulfonate oxygen; the second TPPMS is not coordinated. For Ni2+ the octahedral coordination sphere is composed of water molecules and the TPPMS ligands are not coordinated. Structures are fully reported for [NH4]TPPMS·1/2H2O and [Fe(H2O)5(TPPMS)]TPPMS and partially reported for [Co(H2O)5TPPMS]TPPMS and [Ni(H2O)6]TPPMS2·H2O. All of the structures show hydrophobic regions consisting of aromatic rings and hydrophilic regions with hydrogen-bonding interactions.",

keywords = "Coordination complexes, Hydrophilic interaction, TPPMS, Water-soluble phosphine ligands",

author = "Barton, \{Mark R.\} and Yuegang Zhang and Atwood, \{Jim D.\}",

year = "2002",

doi = "10.1080/0095897022000002295",

language = "English",

volume = "55",

pages = "969--983",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "8",

}

TY - JOUR

T1 - Mono-sulfonated derivatives of triphenylphosphine (see abstract)

AU - Barton, Mark R.

AU - Zhang, Yuegang

AU - Atwood, Jim D.

PY - 2002

Y1 - 2002

N2 - Preparation of the ammonium salt of TPPMS, [NH4]TPPMS, TPPMS = PPh2(m-C6H4SO3-], greatly enhances water solubility and provides an efficient route to other metal complexes of TPPMS, M(TPPMS)2 M = Mn2+, Co2+, Fe2+ and Ni2+. For Co2+ and Fe2+ the metal has an octahedral ligand environment with five water molecules and one TPPMS coordinated through the sulfonate oxygen; the second TPPMS is not coordinated. For Ni2+ the octahedral coordination sphere is composed of water molecules and the TPPMS ligands are not coordinated. Structures are fully reported for [NH4]TPPMS·1/2H2O and [Fe(H2O)5(TPPMS)]TPPMS and partially reported for [Co(H2O)5TPPMS]TPPMS and [Ni(H2O)6]TPPMS2·H2O. All of the structures show hydrophobic regions consisting of aromatic rings and hydrophilic regions with hydrogen-bonding interactions.

AB - Preparation of the ammonium salt of TPPMS, [NH4]TPPMS, TPPMS = PPh2(m-C6H4SO3-], greatly enhances water solubility and provides an efficient route to other metal complexes of TPPMS, M(TPPMS)2 M = Mn2+, Co2+, Fe2+ and Ni2+. For Co2+ and Fe2+ the metal has an octahedral ligand environment with five water molecules and one TPPMS coordinated through the sulfonate oxygen; the second TPPMS is not coordinated. For Ni2+ the octahedral coordination sphere is composed of water molecules and the TPPMS ligands are not coordinated. Structures are fully reported for [NH4]TPPMS·1/2H2O and [Fe(H2O)5(TPPMS)]TPPMS and partially reported for [Co(H2O)5TPPMS]TPPMS and [Ni(H2O)6]TPPMS2·H2O. All of the structures show hydrophobic regions consisting of aromatic rings and hydrophilic regions with hydrogen-bonding interactions.

KW - Coordination complexes

KW - Hydrophilic interaction

KW - TPPMS

KW - Water-soluble phosphine ligands

UR - https://www.scopus.com/pages/publications/0036319384

U2 - 10.1080/0095897022000002295

DO - 10.1080/0095897022000002295

M3 - Article

AN - SCOPUS:0036319384

SN - 0095-8972

VL - 55

SP - 969

EP - 983

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 8

ER -

Mono-sulfonated derivatives of triphenylphosphine (see abstract)

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Keywords

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