Methyl Transfer Reactions to Tetracarbonylferrate(2−): Rate and Mechanistic Studies

Ping Wang; Jim D. Atwood

doi:10.1021/om00034a077

Methyl Transfer Reactions to Tetracarbonylferrate(2−): Rate and Mechanistic Studies

Ping Wang
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Comment/debate

15 Scopus citations

Abstract

Reactions of Na₂Fe(CO)₄ with MeMn(CO)₅ and MeMoCp(CO)₃ result in transfer of the methyl group and formation of MeFe(CO)₄- and Mn(CO)₅- or CpMo(CO)₃-, respectively. These reactions are first order in [Fe(CO)42−] and in the concentration of methyl complex. The reaction of Na₂Fe(CO)₄ with MeRe(CO)₅ is quite slow and produces a mixture of products. No reaction is observed between Na₂Fe(CO)₄ and MeFeCp(CO)₂.

Original language	English
Pages (from-to)	4247-4249
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	10
DOIs	https://doi.org/10.1021/om00034a077
State	Published - 1993

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@article{7115808e93db4be5a033f36a8a539eae,

title = "Methyl Transfer Reactions to Tetracarbonylferrate(2−): Rate and Mechanistic Studies",

abstract = "Reactions of Na2Fe(CO)4 with MeMn(CO)5 and MeMoCp(CO)3 result in transfer of the methyl group and formation of MeFe(CO)4- and Mn(CO)5- or CpMo(CO)3-, respectively. These reactions are first order in [Fe(CO)42−] and in the concentration of methyl complex. The reaction of Na2Fe(CO)4 with MeRe(CO)5 is quite slow and produces a mixture of products. No reaction is observed between Na2Fe(CO)4 and MeFeCp(CO)2.",

author = "Ping Wang and Atwood, \{Jim D.\}",

year = "1993",

doi = "10.1021/om00034a077",

language = "English",

volume = "12",

pages = "4247--4249",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Methyl Transfer Reactions to Tetracarbonylferrate(2−)

T2 - Rate and Mechanistic Studies

AU - Wang, Ping

AU - Atwood, Jim D.

PY - 1993

Y1 - 1993

N2 - Reactions of Na2Fe(CO)4 with MeMn(CO)5 and MeMoCp(CO)3 result in transfer of the methyl group and formation of MeFe(CO)4- and Mn(CO)5- or CpMo(CO)3-, respectively. These reactions are first order in [Fe(CO)42−] and in the concentration of methyl complex. The reaction of Na2Fe(CO)4 with MeRe(CO)5 is quite slow and produces a mixture of products. No reaction is observed between Na2Fe(CO)4 and MeFeCp(CO)2.

AB - Reactions of Na2Fe(CO)4 with MeMn(CO)5 and MeMoCp(CO)3 result in transfer of the methyl group and formation of MeFe(CO)4- and Mn(CO)5- or CpMo(CO)3-, respectively. These reactions are first order in [Fe(CO)42−] and in the concentration of methyl complex. The reaction of Na2Fe(CO)4 with MeRe(CO)5 is quite slow and produces a mixture of products. No reaction is observed between Na2Fe(CO)4 and MeFeCp(CO)2.

UR - https://www.scopus.com/pages/publications/0005729697

U2 - 10.1021/om00034a077

DO - 10.1021/om00034a077

M3 - Comment/debate

AN - SCOPUS:0005729697

SN - 0276-7333

VL - 12

SP - 4247

EP - 4249

JO - Organometallics

JF - Organometallics

IS - 10

ER -

Methyl Transfer Reactions to Tetracarbonylferrate(2−): Rate and Mechanistic Studies

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