Mechanistic insights into hydride transfer for catalytic hydrogenation of CO2 with cobalt complexes

N. Kumar; D. M. Camaioni; M. Dupuis; S. Raugei; A. M. Appel

doi:10.1039/c4dt01551g

Mechanistic insights into hydride transfer for catalytic hydrogenation of CO₂ with cobalt complexes

N. Kumar
, D. M. Camaioni
, M. Dupuis
, S. Raugei
, A. M. Appel

Department of Chemical and Biological Engineering

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The catalytic hydrogenation of CO₂ to formate by Co(dmpe) ₂H can proceed via direct hydride transfer or via CO₂ coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into designing catalysts with improved performance. This journal is

Original language	English
Pages (from-to)	11803-11806
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	31
DOIs	https://doi.org/10.1039/c4dt01551g
State	Published - Aug 21 2014

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abstract = "The catalytic hydrogenation of CO2 to formate by Co(dmpe) 2H can proceed via direct hydride transfer or via CO2 coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into designing catalysts with improved performance. This journal is",

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AU - Appel, A. M.

PY - 2014/8/21

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AB - The catalytic hydrogenation of CO2 to formate by Co(dmpe) 2H can proceed via direct hydride transfer or via CO2 coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into designing catalysts with improved performance. This journal is

UR - https://www.scopus.com/pages/publications/84904415904

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DO - 10.1039/c4dt01551g

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Mechanistic insights into hydride transfer for catalytic hydrogenation of CO₂ with cobalt complexes

Abstract

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