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Measurement of the valence band-offset in a PbSe/ZnO heterojunction by x-ray photoelectron spectroscopy

  • Lin Li
  • , Jijun Qiu
  • , Binbin Weng
  • , Zijian Yuan
  • , Xiaomin Li
  • , Xiaoyan Gan
  • , Ian R. Sellers
  • , Zhisheng Shi
  • University of Oklahoma
  • Harbin Normal University
  • CAS - Shanghai Institute of Ceramics

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

A heterojunction of PbSe/ZnO has been grown by molecular beam epitaxy. X-ray photoelectron spectroscopy was used to directly measure the valence-band offset (VBO) of the heterojunction. The VBO, Δ E V, was determined as 2.51 ± 0.05 eV using the Pb 4p3/2 and Zn 2p3/2 core levels as a reference. The conduction-band offset, Δ E C, was, therefore, determined to be 0.59 ± 0.05 eV based on the above Δ E V value. This analysis indicates that the PbSe/ZnO heterojunction forms a type I (Straddling Gap) heterostructure.

Original languageEnglish
Article number261601
JournalApplied Physics Letters
Volume101
Issue number26
DOIs
StatePublished - Dec 24 2012

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